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An Overview of Dissolved and Suspended Matter Fluxes in the Loire River Basin: Natural and Anthropogenic Inputs
Authors:Cécile Grosbois  Philippe Négrel  Daniel Grimaud  Christian Fouillac
Institution:(1) BRGM, Avenue C. Guillemin, BP 6009, 45060 Orléans Cedex 01, France;(2) Université de Tours, G.E.E.A.C. Faculté des Sciences et Techniques, Parc de Grandmont, 37200 Tours, France;(3) Present address: Laboratorie de Géologie appliquée, UA 1367, BP 0123, 4, place Jussieu, 75252 Paris, France
Abstract:The spatial and temporal distributions of major elements were investigated in the surface waters and in associated suspended matter at two sites of the upper Loire basin (Orleans and Brehemont) between 1995 and 1998.According to geochemical and isotopic patterns, the dissolved load appears to result from a process of mixing rainwater inputs, weathering processes of carbonate and silicate bedrock, and agricultural and urban inputs. Natural inputs influence 60% of water chemical composition at both sites. Annual dissolved fluxes were estimated to be 1300 103 t/y at Orleans and 1620 103 t/y at Brehemont. Major elements are transported mainly in the dissolved fraction. After correcting for atmospheric and anthropogenic inputs, the silicate specific export rate was calculated to be 11 t/y/km2 throughout the basin and the carbonate specific export rate to be from 47 t/y/km2 at Orleans to 23 t/y/km2 at Brehemont.The suspended load appears to result from at least two particle reservoirs: a silicate reservoir and a carbonate reservoir. The silicate reservoir has a detrital origin, mainly during periods of high flow, while the carbonate reservoir has a detrital origin during periods of high flow and an authigenic origin during periods of low flow. Of the total annual flow of suspended matter, this authigenic material represents 16% at Orleans, 25% at Brehemont and 37% in the fluvial part of the estuary. After correcting authigenic inputs, the specific export rate due to mechanical weathering was estimated to be 8 t/y/km2 throughout the Loire basin.
Keywords:anthropogenic inputs  authigenic calcite  dissolved load  flux calculation  Loire River  natural inputs  suspended matter
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