Hazardous gas emissions from the flanks of the quiescent Colli Albani volcano (Rome,Italy) |
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| Authors: | ML Carapezza F Barberi M Ranaldi T Ricci L Tarchini J Barrancos C Fischer D Granieri C Lucchetti G Melian N Perez P Tuccimei A Vogel K Weber |
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| Institution: | 1. Istituto Nazionale di Geofisica e Vulcanologia, Via di Vigna Murata 605, 00143 Rome, Italy;2. Department of Geological Sciences, Roma Tre University, L.go San L. Murialdo 1, 00146 Rome, Italy;3. Environmental Research Division, Instituto Tecnologico y de Energias Renovables (ITER), 38594 Granadilla, Tenerife, Spain;4. Environmental Measurement Techniques, University of Applied Sciences Duesseldorf, Josef-Gockeln-Str. 9, D-40474 Duesseldorf, Germany;5. Istituto Nazionale di Geofisica e Vulcanologia, Via della Faggiola 32, 56126 Pisa, Italy |
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| Abstract: | Gas hazard was evaluated in the three most important cold gas emission zones on the flanks of the quiescent Colli Albani volcano. These zones are located above structural highs of the buried carbonate basement which represents the main regional aquifer and the main reservoir for gas rising from depth. All extensional faults affecting the limestone reservoir represent leaking pathways along which gas rises to the surface and locally accumulates in shallow permeable horizons forming pressurized pockets that may produce gas blowout when reached by wells. The gas, mainly composed of CO2 (>90 vol.%), contains appreciable quantities of H2S (0.35–6 vol.%), and both represent a potentially high local hazard. Both gases are denser than air and accumulate near ground where they may reach hazardous concentrations, and lethal accidents frequently occur to animals watering at local ponds. In order to evaluate the rate of degassing and the related hazard, CO2 and H2S diffuse soil flux surveys have been repeatedly carried out using an accumulation chamber. The viscous gas flux of some important discrete emissions has been evaluated and the CO2 and H2S air concentration measured by portable devices and by Tunable Diode Laser profiles. The minimum potential lethal concentration of the two gases (250 ppm for H2S and 8 vol.% for CO2) is 320 times higher for CO2, whereas the CO2/H2S concentration ratio in the emitted natural gas is significantly lower (15–159). This explains why H2S reaches hazardous, even lethal, concentrations more frequently than CO2. A relevant hazard exists for both gases in the depressed zones (channels, excavations) particularly in the non-windy early hours of the day. |
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