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烷烃与海水界面张力的研究
引用本文:陈国华,佘敬曾,郭玲,黄健,朱茜,刘清锐,杨文利.烷烃与海水界面张力的研究[J].海洋与湖沼,1996,27(2):213-219.
作者姓名:陈国华  佘敬曾  郭玲  黄健  朱茜  刘清锐  杨文利
作者单位:青岛海洋大学化学系!青岛,266003,青岛海洋大学化学系!青岛,266003,青岛海洋大学化学系!青岛,266003,青岛海洋大学化学系!青岛,266003,青岛海洋大学化学系!青岛,266003,青岛海洋大学化学系!青岛,266003,青岛海洋大学化学系!青岛,266003
基金项目:国家自然科学基金,国家海洋局科技发展基金!49070272
摘    要:于1991年3月-1992年6月间用滴体积法较系统地测定正已烷、正庚烷、正辛烷、异辛烷、正十二烷、正十六烷和煤油与海水在不同的温度(16-40℃)和盐度(10-40)范围内的界面张力,测定值的相对误差≤0.5%。对数据进行统计处理后,归纳出所研究烷烃-海水界面张力与温度和盐度的经验关系式,计算与实验值相对误差≤0.5%。

关 键 词:烷烃  海水界面  界面张力  经验关系式
收稿时间:1992/9/10 0:00:00
修稿时间:1994/8/23 0:00:00

STUDY ON ALKANE-SEAWATER INTERFACIAL TENSION
Chen Guohu,She Jingzeng,Guo Ling,Huang Jian,Zhu Qian,Liu Qingrui and Yang Wenli.STUDY ON ALKANE-SEAWATER INTERFACIAL TENSION[J].Oceanologia Et Limnologia Sinica,1996,27(2):213-219.
Authors:Chen Guohu  She Jingzeng  Guo Ling  Huang Jian  Zhu Qian  Liu Qingrui and Yang Wenli
Institution:Department of Marine Chemistry, Ocean University of Qingdao, Qingdao 266003;Department of Marine Chemistry, Ocean University of Qingdao, Qingdao 266003;Department of Marine Chemistry, Ocean University of Qingdao, Qingdao 266003;Department of Marine Chemistry, Ocean University of Qingdao, Qingdao 266003;Department of Marine Chemistry, Ocean University of Qingdao, Qingdao 266003;Department of Marine Chemistry, Ocean University of Qingdao, Qingdao 266003;Department of Marine Chemistry, Ocean University of Qingdao, Qingdao 266003
Abstract:The respective alkane (n-c6, n-c7, n-c8,i-8, n-c12, n-c16 and kerosene, respectively)-seawater interfacial tension (I.T. ) in the temperature range of 16 - 40 °C and salinity range of 10 - 40 were determined with the drop-volume method by the authors from 1991 to 1992. The relative standard deviation of measured values <=0.5%. Seven empirical equations obtained on the basis of these measurements directly relates the alkanes-seawater I.T. with the temperature and salinity. The results show that all the alkanes-seawater I. T. decrease linearly with the rise of temperature. The salinity coefficient of the (n-c6, n-c7, n-c8, and i-c8)-seawater I.T. is positive, negative for n-c12 or n-c16. A model of adsorption at the alkane-seawater interface is presented for interpretation of this change of I .T. with salinity.
Keywords:Alkane-seawater interface Interfacial tension Experimental equation
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