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Phase equilibria and physical properties
Authors:Richard J O'Connell
Abstract:The average physical properties of multiphase aggregates, such as rocks, depend on the properties of the individual phases as well as the statistical spatial distribution of the phases, such as the relative concentrations, and the shape, orientation, and distribution of the grains of the individual phases. If the properties of the phases are similar, the aggregate properties depend mainly on volume averages of properties of the phases; this is the case for elastic properties of rocks. If the properties of the phases differ significantly, the geometric distribution of the phases becomes important; this is the case if a fluid phase is present, which may have a large effect on elastic and electrical properties. Laboratory measurements of properties of individual phases and aggregates, used with theoretical treatments of aggregate properties, permits the interpretation of seismic velocities, attenuation and electrical conductivity in the earth in terms of possible compositions, phases and distribution of phases, such as intergranular fluids.
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