Aspects of U-Th fractionation in Tertiary limestones and calcretes of Dhofar,southern Oman |
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| Authors: | Bernhard Pracejus Narasimman Sundararajan Salah Al-Khirbash Talal Al-Hosni A Ebrahimi Shakil Al-Bulushi Ali Al-Lazki Musadem Al-Maashani |
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| Institution: | 1. Earth Science Department, Sultan Qaboos University, P.O. Box 36, 123 Al-Khoud, Muscat, Oman;2. Petroleum Development Oman (PDO), Mina Al-Fahal, Muscat, Oman;3. Ministry of Commerce & Industry, Muscat, Oman |
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| Abstract: | This paper presents findings from a comprehensive geochemical and geophysical re-examination of known radiogenic anomalies in Tertiary limestones and (sub-)recent calcretes of southwestern Dhofar in the Sultanate of Oman. U-Th-enrichments seem to be associated with deep-rooted fault systems that cross-cut Corg-rich shales at depths of some 800–1000?m, which generally show elevated gamma-ray levels in southern Oman and act as the initial geochemical trap. Metals and radiogenic elements, such as K (max?1945?ppm), U (max?44?ppm), and Th (max?26?ppm) mobilised from these rocks and emplaced higher up in the faults must have constituted radiogenic lineaments at and near the surface (observed in a different but difficult to access location). However, successive weathering partially obscured such anomalies through further re-mobilisation/-mineralisation processes within the calcretes that also enriched Sr and V. In these carbonates, uranium correlates positively with Sr but not very well with V, while thorium shows moderate positive correlations with Sr and V. Both U and Th are also not present (i.e., below the detection limits of a few ppm) in a second sample group that represents background conditions. Being much more immobile than U, Th remained closer to the original western fault positions of the examined site (outlined by magnetics and VLF-EM during the surveys), while uranium moved down-dip over the plateau and through underlying sub-horizontal strata towards the eastern fault system. Here, supergene Sr-enriched calcite preferentially incorporated U, thus reflecting the observed U-Th fractionation. |
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| Keywords: | Uranium-thorium fractionation Limestone Calcrete Dhofar Oman |
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