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层控夕卡岩及有关矿床形成过程的稀土元素行为——以安徽冬瓜山矿床为例
引用本文:凌其聪,刘从强.层控夕卡岩及有关矿床形成过程的稀土元素行为——以安徽冬瓜山矿床为例[J].岩石学报,2003,19(1):192-200.
作者姓名:凌其聪  刘从强
作者单位:1. 中国科学院地球化学研究所,地球深部物质与流体作用地球化学实验室,贵阳,550002;中国地质大学地球科学学院,武汉,430074
2. 中国科学院地球化学研究所,地球深部物质与流体作用地球化学实验室,贵阳,550002
基金项目:科技部“九五”攀登预选项目(95-预-39),国家自然科学基金(49633120),国家杰出青年科学家基金(49625304)
摘    要:对安徽省冬瓜山层控夕卡岩型铜(金)矿床中穿层方向上不同蚀变程度的大理岩,顺层方向上距岩体远近不同但垂向深度的块状石榴子石夕卡岩及其主矿物石榴子石,不同演化阶段的石英及矿石等到的REE特征进行了系统研究,结果显示,在穿层方向上,大理岩被交代的程度愈深其稀土总量(∑REE)愈高,Eu负异常愈显著,尽管,夕卡岩全岩的RE分布模式与原岩(大理岩)相似,但前者的稀土总量(∑REE)远高于后者,且Eu异常更为显著,显然不是继续承原岩的REE特征所致,而是受控于其主矿物石榴子石的REE特征,后者又由参与交代作用的岩浆热液REE所决定,热液中的REE具有缓和右倾型分布模式,LREE富集,较显著的Eu负异常等基本特征,石榴子石晶体基本承袭了热液的REE特征,REE的空间变化特征结果地层的构造特征可以揭示夕卡岩及相关矿体形成过程中流体的输运径及输运方式,REE的研究有助于深化对层控夕卡岩及其相关矿床形成过程的认识。

关 键 词:安徽  REE行为  流体地球化学  层控夕卡岩  稀土元素  铜矿床  金矿床  成矿环境
文章编号:1000-0569/2003/019(01)-0192-00
修稿时间:2001年9月21日

REE behavior during formation of strata-bound skarn and related deposit: a case study of Dongguashan skarn deposit in Anhui province, China.
LING QiCong and LIU CongQiang . Laboratory for Study the Earth's Interior and Geofluids.REE behavior during formation of strata-bound skarn and related deposit: a case study of Dongguashan skarn deposit in Anhui province, China.[J].Acta Petrologica Sinica,2003,19(1):192-200.
Authors:LING QiCong and LIU CongQiang  Laboratory for Study the Earth's Interior and Geofluids
Institution:LING QiCong and LIU CongQiang . Laboratory for Study the Earth's Interior and Geofluids,Institute of Geochemistry,Chinese Academy of Sciences,Guiyang,China. Faculty of Earth Sciences,China University of Geosciences,Wuhan,China
Abstract:Systematic studies have been carried out on REE compositions of hydrothermai alterated marbles, massive garnet skarns and ores, as well as garnet and quartz formed in multi-stage skarn and deposit formation. The results show that strata-bound skarn and its related Cu deposits were formed in a complex hydrothermai system during multi-sage infiltration metasomatism. The REE characteristics of skarns, however, are similar to those of the marbles. They were not simply inherited from the marble protolith, but were controlled by garnets, and the latter's were determined by the hydrothermai solutions participating infiltration metasomatism. The related hydrothermai fluids characterized with slightly right-hand dip REE patterns, are enriched in LREE and have strong negative Eu anomalies. The uptake of REE from hydrothermai fluid during garnet crystallization resulted in that garnet shared the similar REE patterns. REE in skarns were provided mainly by hydrothermai fluids associated with the emplacement of granodiorite plutons in the mining district. Based on the dimensional variation of REE in skarns combining with the structures of hosting strata, the transporting route and pattern of fluids involved in the formation of skarns and related deposits can be better understood. The present study demonstrates that extensive REE metasomatism can occur in hydrothermai system at shallow to intermediate depths and REE geochemistry are useful in discerning the origin of skarns and skarn-related deposits.
Keywords:REE behavior  Hydrothermal geochemistry  Strata-bound skarn  Dongguashan Cu(Au) deposit
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