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Perfluorinated compounds in blood of Caretta caretta from the Mediterranean Sea
Authors:Cristiana Guerranti  Stefania Ancora  Nicola Bianchi  Guido Perra  Emiliano Leonida Fanello  Simonetta Corsolini  Maria Cristina Fossi  Silvano Ettore Focardi
Institution:1. Department of Physical, Earth and Environmental Sciences, University of Siena, Via Mattioli 4, 53100 Siena, Italy;2. Institute of Clinical Physiology, National Research Council (CNR), Via Moruzzi 1, 56100 Pisa, Italy
Abstract:Perfluorinated compounds (PFCs), widely used for their hydro-oil repellent properties, are almost non-degradable in the environment; there is scientific evidence that indicate bioaccumulation. They represent a threat to many organisms, because they are toxic and are endocrine disruptors. Scientific studies have demonstrated the presence of PFCs in blood and liver samples of fish, turtles, birds and mammals of marine ecosystems in different geographical areas. The aim of this study was to determine the distribution of PFOS and PFOA in blood samples of the marine turtle Caretta caretta, using a minimally invasive sampling procedure. 49 blood samples of marine turtle, taken from several Italian marine turtle rescue centers, were analyzed. While PFOA was never detected, measurable concentrations of PFOS were found in 15 blood samples; the values show a range from 1.14 ng/g to 28.51 ng/g (wet wt.). No differences between groups of samples taken from different areas were found.
Keywords:PFOS  PFOA  HPLC-MS  Endocrine disruptors  Marine turtle rescue centers
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