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New England granites: Trace element evidence regarding their origin and differentiation
Authors:Grant Buma  Fred A Frey  David R Wones
Institution:(1) Department of Earth and Planetary Sciences, Massachusetts Institute of Technology, 02139 Cambridge, Massachusetts;(2) Present address: Kennecott Copper Corp., 1515 Mineral Square, 84111 Salt Lake City, Utah, USA
Abstract:The abundances of Sc, rare earths, Zr, Hf, Ta and Th were determined in five New England granitic plutons. Similar data are reported for separated minerals from three of the units. The granites can be divided into the Massachusetts alkaline group (Cape Ann, Peabody, Quincy) and the Rhode Island subalkaline group (Narragansett Pier, Westerly).Analyses for three samples from each pluton indicate that the Westerly granite is heterogeneous in both major and trace elements. Th abundances vary considerably (factor of 2) in both Rhode Island granites. Zr and Hf are heterogeneously distributed in all the granites while the rare earths are more homogeneous (< ± 20% deviation from mean).Eu depletions in all the granites imply that feldspar was involved either as a cumulate during fractional crystallization or as a residual phase during anatexis. Because the Massachusetts granites are associated with syenites and show evidence for low water fugacity and denser rocks at depth, these granites probably developed from basic magmas as a result of extensive feldspar crystallization.Depletion of Tb, Dy, Yb, Lu, Zr, Hf and Ta in the Rhode Island granites suggest participation of zircon or garnet as residues of partial melting or as crystal cumulates. These granites crystallized under nearly water saturated conditions and are characterized by abundant pegmatites. The presence of a water rich phase may also have been important in the depletion of elements which form stable complexes in aqueous solutions.
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