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Heavily metamorphosed clasts from the CV chondrite breccias Mokoia and Yamato‐86009
Authors:Kaori JOGO  Kazuhide NAGASHIMA  Ian D HUTCHEON  Alexander N KROT  Tomoki NAKAMURA
Institution:1. School of Ocean, Earth Science and Technology, Hawai’i Institute of Geophysics and Planetology, University of Hawai’i at Mānoa, Honolulu, Hawai’i 96822, USA;2. NASA Astrobiology Institute, University of Hawai’i at Mānoa, Honolulu, Hawai’i 96822, USA;3. Glenn Seaborg Institute, Lawrence Livermore National Laboratory, Livermore, California 94551, USA;4. Department of Earth and Planetary Materials Science, Faculty of Science, Laboratory for Early Solar System Evolution, Tohoku University, Sendai, Miyagi 980‐8578, Japan
Abstract:Abstract– Metamorphosed clasts in the CV carbonaceous chondrite breccias Mokoia and Yamato‐86009 (Y‐86009) are coarse‐grained, granular, polymineralic rocks composed of Ca‐bearing (up to 0.6 wt% CaO) ferroan olivine (Fa34–39), ferroan Al‐diopside (Fs9–13Wo47–50, approximately 2–7 wt% Al2O3), plagioclase (An37–84Ab63–17), Cr‐spinel (Cr/(Cr + Al) = 0.19–0.45, Fe/(Fe + Mg) = 0.60–0.79), nepheline, pyrrhotite, pentlandite, Ca‐phosphate, and rare grains of Ni‐rich taenite; low‐Ca pyroxene is absent. Most clasts have triple junctions between silicate grains, indicative of prolonged thermal annealing. Based on the olivine‐spinel and pyroxene thermometry, the estimated metamorphic temperature recorded by the clasts is approximately 1100 K. Few clasts experienced thermal metamorphism to a lower degree and preserved chondrule‐like textures. The Mokoia and Y‐86009 clasts are mineralogically unique and different from metamorphosed chondrites of known groups (H, L, LL, R, EH, EL, CO, CK) and primitive achondrites (acapulcoites, brachinites, lodranites). On a three‐isotope oxygen diagram, compositions of olivine in the clasts plot along carbonaceous chondrite anhydrous mineral line and the Allende mass‐fractionation line, and overlap with those of the CV chondrule olivines; the Δ17O values of the clasts range from about ?4.3‰ to ?3.0‰. We suggest that the clasts represent fragments of the CV‐like material that experienced metasomatic alteration, high‐temperature metamorphism, and possibly melting in the interior of the CV parent asteroid. The lack of low‐Ca pyroxene in the clasts could be due to its replacement by ferroan olivine during iron‐alkali metasomatic alteration or by high‐Ca ferroan pyroxene during melting under oxidizing conditions.
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