Arsenic mobility in groundwater/surface water systems in carbonate-rich Pleistocene glacial drift aquifers (Michigan) |
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| Institution: | 1. Earth and Environmental Systems Institute, The Pennsylvania State University, University Park, PA, United States;2. CICTERRA-CONICET Facultad de Ciencias Exactas, Físicas y Naturales Universidad Nacional de Córdoba Córdoba, Argentina;3. Department of Geosciences, The Pennsylvania State University, University Park, PA, United States;1. Department of Geography-Earth Science, Shippensburg University of Pennsylvania, 1871 Old Main Dr., Shippensburg, PA 17257-2299, USA;2. Department of Physical Sciences, Kutztown University of Pennsylvania, Boehm Science Center 138, Kutztown, PA 19530, USA;3. Geochronology Laboratory, Illinois State Geological Survey, Prairie Research Institute, University of Illinois at Urbana-Champaign, 615 E. Peabody Dr., Champaign, IL 61820, USA;1. Department of Marine, Earth, and Atmospheric Sciences, North Carolina State University, Raleigh, NC 27695, United States;2. Department of Earth and Environmental Sciences, University of Michigan, Ann Arbor, MI 48109, United States |
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| Abstract: | Within the Lower Peninsula of Michigan, groundwaters from the Marshall Formation (Mississippian) contain As derived from As-rich pyrites, often exceeding the World Heath Organization drinking water limit of 10 μg/L. Many Michigan watersheds, established on top of Pleistocene glacial drift derived from erosion of the underlying Marshall Formation, also have waters with elevated As. The Huron River watershed in southeastern Lower Michigan is a well characterized hydrogeochemical system of glacial drift deposits, proximate to the Marshall Fm. subcrop, which hosts carbonate-rich groundwaters, streams, and wetlands (fens), and well-developed soil profiles. Aqueous and solid phase geochemistry was determined for soils, soil waters, surface waters (streams and fens) and groundwaters from glacial drift aquifers to better understand the hydrogeologic and chemical controls on As mobility. Soil profiles established on the glacial drift exhibit enrichment in both Fe and As in the oxyhydroxide-rich zone of accumulation. The amounts of Fe and As present as oxyhydroxides are comparable to those reported from bulk Marshall Fm. core samples by previous workers. However, the As host in core samples is largely unaltered pyrite and arsenopyrite. This suggests that the transformation of Fe sulfides to Fe oxyhydroxides largely retains As and Fe at the oxidative weathering site. Groundwaters have the highest As values of all the waters sampled, and many were at or above the World Health limit. Most groundwaters are anaerobic, within the zones of Fe3+ and As(V) reduction. Although reduction of Fe(III) oxyhydroxides is the probable source of As, there is no correlation between As and Fe concentrations. The As/Fe mole ratios in drift groundwaters are about an order of magnitude greater than those in soil profiles, suggesting that As is more mobile than Fe. This is consistent with the dominance of As(III) in these groundwaters and with the partitioning of Fe2+ into carbonate cements. Soil waters have very low As and Fe contents, consistent with the stability of oxyhydroxides under oxidizing vadose conditions. When CO2 charged groundwaters discharge in streams and fens, dissolved As is effectively removed by adsorption onto Fe-oxides or carbonate marls. Although Fe does not display conservative behavior with As in groundwaters, a strong positive correlation exists between As and Sr concentrations. As water–rock interactions proceed, the As/Fe and Sr/Ca ratios would be expected to increase because both As and Sr behave as incompatible elements. Comparisons with groundwater chemistries from other drift-hosted aquifers proximate to the Marshall sandstone are consistent with these relations. Thus, the Sr content of carbonate-rich groundwaters may provide useful constraints on the occurrence, origin and evolution of dissolved As in such systems. |
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