| Abstract: | The natural remanent magnetization of andesitic pumice emitted during the 1985 eruption of the Nevado del Ruiz volcano (Colombia) has a direction opposite to the present geomagnetic field. The self-reversing mechanism can be re-activated in the laboratory during cycles of heating and subsequent cooling in air and zero magnetic field. Laboratory-produced thermoremanent magnetization is dominated by the same self-reversal process in fields up to several mT. Microchemical, optical and Curie temperature analyses indicate that the ferromagnetic minerals are members of the magnetite-ulvöspinel and hematite-ilmenite series with average compositions of Fe2.73Ti0.27O4 and Fe1.38Ti0.62O3, respectively. In analogy with the magnetic behaviour of synthetically grown antiferromagnetic-ferromagnetic FeMn-FeNi films, the self-reversal can probably be interpreted in terms of an exchange field acting between a Ti-poor canted antiferromagnetic and a Ti-rich ferrimagnetic phase in the hemoilmenite grains. |
