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3He4He ratio,noble gas abundance and K-Ar dating of diamonds—An attempt to search for the records of early terrestrial history
Authors:M Ozima  S Zashu  O Nitoh
Institution:1. Geophysical Institute, University of Tokyo, Tokyo 113, Japan;7. Faculty of Engineering, Tokyo University of Agriculture and Technology, Koganei-city, 184, Japan
Abstract:The 3He4He ratios measured in 27 Southern Africa diamond stones, four from Premier Mine and the rest of unidentified origin, range from 4.2 × 10?8 to 3.2 × 10?4, with three stones above 1 × 10?4. We conclude that the initial helium isotopic ratio (3He4He)0 in the earth was significantly higher than that of the planetary helium-A (3He4He = 1.42 × 10?4), but close to the solar helium (3He4He ? 4 × 10?4).The apparent K-Ar ages for the twelve diamonds of unidentified origin show enormously old age, indicating excess argon-40. 3He4He evolution in diamonds suggests that the diamonds with the high 3He4He ratio (>2 × 10?4) may be as old as the earth.Noble gas elemental abundance in the diamonds relative to the air noble gas abundance shows monotonie decrease with a decreasing mass number.This paper discusses the implications of these observations on the early solar system and the origin of diamonds.
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