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Unusual biomarker maturation ratio changes through the oil window, a consequence of varied thermal history
Authors:Christopher P N Davies  
Abstract:Saturated and aromatic biomarker ratios continue to change systematically through the oil window and into the gas-condensate window to high vitrinite reflectances (Ro = 1.16%) in mature marine and lacustrine Mesozoic clastic samples from a South African basin. Two of the ratios reverse above Ro = 0.9%. These unusual maturation effects result from isolated periods of high rates of maturation increase. The basin cooled regionally after the break-up of Gondwana but high heating rates prevailed during the late Cretaceous-early Tertiary, as Africa moved across a hotspot, and again in the late Tertiary as a result of a possible hotspot and hydrothermal event.
Keywords:Biomarkers  Crude petroleum  Vitrinite reflectance  Maturation parameters
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