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New data on alstonite
Authors:Franco Sartori
Institution:Institute of Mineralogy and Petrography, University of Pisa, Italy
Abstract:New chemical and X-ray data on alstonite are reported. These indicate that alstonite is a double salt with formula CaBa(CO2)2 and that it has triclinic symmetry with a prominent orthorhombic pseudo-cell where a′ = 5.02, b′ = 8.70, c′ = 6.12 A?, z = 2, which correspondes closely to Gossner & Mussgnug? cell. The large number of weak super-structure reflections observed shows that the true cell (keeping the setting given by Gossner & Mussnug) has the following parameters: a = 30.14, b= 17.40, c = 6.12 A?, α=β=γ=90°, Z = 24. The possible space groups are C1 and C1. The peculiar features of the diffraction pattern suggest that alstonite is probably an ordered member of a family of possible order-disorder structures.
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