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Alkali metasomatism in the major gneiss,northwest Adirondacks,New York: open system or closed?
Authors:James D Carl
Institution:Department of Geological Sciences, State University College of Arts and Science, Potsdam, NY 13676, U.S.A.
Abstract:The thickest clastic unit in the northwest Adirondacks. New York, undergoes gradual transition from amphibolite to granulite facies over a distance of 55 km from Emeryville to Colton. This Precambrian quartz-biotite-oligoclase-K-feldspar gneiss with migmatite characteristics has long been cited as having undergone progressive loss of K, Si, Fe2+, Ba and H2O toward Colton and granulite facies conditions (Engel and Engel, 1958, 1960a. b). Chemical data obtained from new samples, however, cast doubt upon the interpretation of open system alkali metasomatism. Outcrop to outcrop chemical variation is shown to be of similar magnitude to the chemical variation recorded across the entire gneiss belt. Chemical differences between Emeryville and Colton are not those expected from progressive degranitization by loss of alkali-bearing fluid. Ratios of KRb and Ca-Na K suggest that metamorphism was isochemical on the scale of outcrop. These new data were obtained from mixtures of leucosome and fine-grained paragneiss at each of 7 outcrops. The sampling technique contrasts with that of A.E.J. and C. Engel who analyzed leucosome separately from fine grained (‘least altered’) gneiss.
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