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Reactions to define the biotite isograd in the Ryoke metamorphic belt,Kii Peninsula,Japan
Authors:Ge-Fan Wang  Shohei Banno  Keiji Takeuchi
Institution:(1) Department of Geology and Mineralogy, Faculty of Science, Kyoto University, 606 Kyoto, Japan;(2) Geological Survey of Japan, Higashi 1-1-3, Yatabe, 305 Ibaraki, Japan
Abstract:Two types of biotite isograd are defined in the low-grade metamorphism of the Wazuka area, a Ryoke metamorphic terrain in the Kii Peninsula, Japan. The first, BI1, is defined by the reaction of chlorite+K-feldspar= biotite+muscovite+quartz+H2O that took place in psammitic rocks, and the second, BI2, by the continuous reaction between muscovite, chlorite, biotite and quartz in pelitic rocks. The Fe/Mg ratios of the host rocks do not significantly affect the reactions. From the paragenesis of pelitic and psammitic metamorphic rocks, the following mineral zones were established for this low-pressure regional metamorphic terrain: chlorite, transitional, chlorite-biotite, biotite, and sillimanite. The celadonite content of muscovite solid solution in pelitic rocks decreases systematically with the grade of metamorphism from 38% in the chlorite zone to 11% in the biotite zone. Low pressure does not prohibit muscovite from showing the progressive change of composition, if only rocks with appropriate paragenesis are chosen. A qualitative phase diagram of the AKF system relevant to biotite formation suggests that the higher the pressure of metamorphism, the higher the celadonite content of muscovite at BI1, which is confirmed by comparing the muscovites from the Barrovian and Ryoke metamorphism.
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