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Monte Carlo method applied to modeling copper transport in river sediments |
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| Authors: | Marcela Z Corazza Taufik Abr?o Fábio Grandis Lepri Sonia M N Gimenez Elisabeth Oliveira Maria Josefa Santos |
| Institution: | 1. Chemistry Department, State University of Londrina (DQ-UEL), Londrina, PR, 86051-990, Brazil 2. Electrical Engineering Department, State University of Londrina (UEL), Londrina, PR, Brazil 3. Analytical Chemistry Department, Fluminense Federal University, Niterói, RJ, 24020-141, Brazil 4. Chemistry Institute, University of S?o Paulo (IQ-USP), S?o Paulo, Brazil |
| Abstract: | Monte Carlo simulation (MCS) methodology has been applied to explain the variability of parameters for pollutant transport and fate modeling. In this study, the MCS method was used to evaluate the transport and fate of copper in the sediment of the Tibagi River sub-basin tributaries, Southern Brazil. The statistical distribution of the variables was described by a dataset obtained for copper concentration using sequential extraction, organic matter (OM) amount, and pH. The proposed stochastic spatial model for the copper transport in the river sediment was discussed and implemented by the MCS technique using the MatLab 7.3? mathematical software tool. In order to test some hypotheses, the sediment and the water column in the river ecosystem were considered as compartments. The proposed stochastic spatial model makes it possible to predict copper mobility and associated risks as a function of the organic matter input into aquatic systems. The metal mobility can increase with the OM posing a rising environmental risk. |
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