Fluid regime of the amphibolite-facies metamorphism in the Dzhugdzhur-Stanovoy fold area (Far East) |
| |
| Authors: | O V Avchenko I A Aleksandrov V O Khudolozhkin M A Mishkin |
| |
| Institution: | (1) Far East Geological Institute, Far East Branch, Russian Academy of Sciences, Vladivostok, Russia |
| |
| Abstract: | Chromatographic and electrochemical measurements, combined with computer simulation of the natural mineral parageneses and estimation of the stability field of muscovite-bearing assemblages, yielded a consistent model of the fluid regime for the amphibolite-facies metamorphism of the Dzhugdzhur-Stanovoy fold area (DSFA). The model allows the fluid differentiation into “internal” and “external” fluids. The “internal” fluid is formed by the volatiles of the rock, while the “external” fluid arrived from an outer source: the mantle or other reservoir. It is established that the chromatographic and electrochemical measurements refer to the “external” fluid, whereas the redox state estimated from the mineral equilibria is related to the “internal” fluid, whose composition is buffered by the equilibrium mineral assemblage. The “external” fluid trapped by rocks preserves its own redox state only at the regtrograde stage, when the solid-phase reactions slacken and the buffer role of the mineral assemblages is minimized. This aspect explains the contradiction between the wide variations in the oxidation state of the mineral equilibria (log fO2 from ?15 to ?20), on the one hand, and the persistent oxidation state of the external fluid established by the chromatographic and electrochemical methods, on the other hand. The main reason for the wide development of hornblende-bearing assemblages in the amphibolite-facies metamorphic rocks of the Dzhugdzhur-Stanovoy fold system is the high H2O pressure in the “external” fluid. According to the obtained data, the composition of the “external” fluid is determined by the conditions $ P_{H_2 O} Chromatographic and electrochemical measurements, combined with computer simulation of the natural mineral parageneses and
estimation of the stability field of muscovite-bearing assemblages, yielded a consistent model of the fluid regime for the
amphibolite-facies metamorphism of the Dzhugdzhur-Stanovoy fold area (DSFA).
The model allows the fluid differentiation into “internal” and “external” fluids. The “internal” fluid is formed by the volatiles
of the rock, while the “external” fluid arrived from an outer source: the mantle or other reservoir. It is established that
the chromatographic and electrochemical measurements refer to the “external” fluid, whereas the redox state estimated from
the mineral equilibria is related to the “internal” fluid, whose composition is buffered by the equilibrium mineral assemblage.
The “external” fluid trapped by rocks preserves its own redox state only at the regtrograde stage, when the solid-phase reactions
slacken and the buffer role of the mineral assemblages is minimized. This aspect explains the contradiction between the wide
variations in the oxidation state of the mineral equilibria (log fO2 from −15 to −20), on the one hand, and the persistent oxidation state of the external fluid established by the chromatographic
and electrochemical methods, on the other hand. The main reason for the wide development of hornblende-bearing assemblages
in the amphibolite-facies metamorphic rocks of the Dzhugdzhur-Stanovoy fold system is the high H2O pressure in the “external” fluid. According to the obtained data, the composition of the “external” fluid is determined
by the conditions  ≥ 0.7 PS and  = 0.01–0.3. The oxidation potential of the “external” fluid is close to that of the H2O-C system under carbon-saturated vapor conditions.
Original Russian Text ? O.V. Avchenko, I.A. Aleksandrov, V.O. Khudolozhkin, M.A. Mishkin, 2009, published in Tikhookeanskaya
Geologiya, 2009, Vol. 28, No. 4, pp. 3–15. |
| |
| Keywords: | metamorphic fluid fluid regime electrochemistry gas chromatography oxidation state Dzhugdzhur-Stanovoy fold area |
| 本文献已被 SpringerLink 等数据库收录！ |
|
