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Sigmoidal exsolution by internal shear stress in pyroxenes from chondritic meteorites
Authors:Ferraris  C  Folco  L  Mellini  M
Institution:(1) Dipartimento di Scienze della Terra, Università di Siena, Via Laterina 8, 53100 Siena, Italy;(2) Institute of Environmental Science Engineering, Nanyang Technological University, Innovation Centre Block 2, Unit 247, 18 Nanyang Drive, Singapore, 637723;(3) Museo Nazionale dellrsquoAntartide, Università di Siena, Via Laterina 8, 53100 Siena, Italy
Abstract:Pyroxenes of pigeonitic and augitic bulk compositions in H3–4 chondritic meteorites commonly exhibit sigmoidal precipitates, rather than the elsewhere common lamellar associations. Most often, submicrometric sigmoids with calcic clinopyroxene composition occur within clinoenstatite; more rarely, clinoenstatite sigmoids occur within calcic clinopyroxene. The sigmoids appear as lsquo001rsquo terminated lamellae, with terminations rotated in opposite directions towards the lsquo100rsquo orientation. Pre-exsolution pigeonite and augite formed at temperatures higher than 980 °C, whereas sigmoidal exsolution occurred between 990 and 830 °C. Local anomalous lattice parameters determined by electron diffraction suggest that lattice parameters are most strained where the exsolution texture is most poorly defined. Shear strain occurs during exsolution due to mismatching lattice parameters and variable beta angles. In response to shear stress, the lamellae relax and assume sigmoidal strained morphologies. Sigmoidal exsolution is strongly controlled by (100) orthoenstatite stacking faults that possibly trigger exsolution.
Keywords:Exsolution  Pyroxene  Chondrule  Sigmoids  Shear stress
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