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Polymorphism in sapphirine
Authors:Stefano Merlino
Institution:(1) Institute of Mineralogy and Petrography, University of Pisa, Italy
Abstract:Sapphirine-1Tc, a polymorph of sapphirine, was found in granulites near Wilson Lake, Labrador. It is triclinic with unit cell data: a=10.04, b=10.38, c=8.65 Å, agr=107°33prime, beta=95°07prime, gamma=123°55prime. The X-ray diffraction patterns of several crystals of sapphirine from Wilson Lake were investigated and evidence was found of solid state reactions that lead from the ordered polymorph-1Tc to a disordered arrangement of domains with the structure of sapphirine-2M, that is ldquonormalrdquo sapphirine.
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