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On leakage and seepage of CO2 from geologic storage sites into surface water
Authors:C M Oldenburg  J L Lewicki
Institution:(1) Earth Sciences Division 90-1116, Ernest Orlando Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA
Abstract:Geologic carbon sequestration is the capture of anthropogenic carbon dioxide (CO2) and its storage in deep geologic formations. The processes of CO2 seepage into surface water after migration through water-saturated sediments are reviewed. Natural CO2 and CH4 fluxes are pervasive in surface-water environments and are good analogues to potential leakage and seepage of CO2. Buoyancy-driven bubble rise in surface water reaches a maximum velocity of approximately 30 cm s−1. CO2 rise in saturated porous media tends to occur as channel flow rather than bubble flow. A comparison of ebullition versus dispersive gas transport for CO2 and CH4 shows that bubble flow will dominate over dispersion in surface water. Gaseous CO2 solubility in variable-salinity waters decreases as pressure decreases leading to greater likelihood of ebullition and bubble flow in surface water as CO2 migrates upward.
Keywords:Ebullition  CO2 storage  Leakage  Seepage  Bubble flow
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