Mineralogical Associations of Arsenic and Antimony in Thirty Five Geochemical Reference Materials by Sequential Extraction with Hydride Generation and Atomic Absorption Spectrometry |
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| Authors: | Shigeru Terashima Masahiro Taniguchi |
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| Institution: | Geological Survey of Japan, 1-1-3 Higashi, Tsukuba, Ibaraki 305-0046, Japan. e-mail: |
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| Abstract: | A method is described to estimate the chemical forms of arsenic (As) and antimony (Sb) in a variety of geochemical reference materials, combining a sequential extraction scheme with hydride generation and atomic absorption spectrometry (HG-AAS). The fractions dissolved by sequential extraction are empirically defined as the exchangeable, EDTA soluble, oxide, sulfide and residual fractions. The amount of As and Sb in the EDTA soluble fraction have been derived mainly from oxide phases, and partly from carbonate minerals. Most sulfide minerals in common geological samples were considered to be dissolved with the digestion of 0.7 mol l?1 NaOCl, but only small fraction of arsenopyrite and loellingite in ores could be dissolved in this way. Satisfactory agreement was observed between the sum of the As or Sb values from exchangeable to residual fractions and the reported total As or Sb values, with a few exceptions. Analytical results of As and Sb for thirty five geochemical reference materials are tabulated, and geochemical and mineralogical features are discussed. |
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