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An epigenetic origin for the Passagem de Mariana gold deposit, Quadrilátero Ferrífero, Minas Gerais, Brazil
Authors:DS Vial  BP Duarte  K Fuzikawa  MBH Vieira
Institution:aCVRD — Companhia Vale do Rio Doce, BR381, Km 459, Santa Luzia, MG, Brazil;bFaculdade de Geologia da Universidade do Estado do Rio de Janeiro, Rua São Francisco Xavier, 524, Maracanã, Rio de Janeiro, RJ, Brazil;cCDTN-Centro de Desenvolvimento da Tecnologia Nuclear, Rua Mário Werneck, s/n, Campus UFMG, Pampulha, Belo Horizonte, MG, Brazil;dCompanhia Vale do Rio Doce, BR262, Km 296, Santa Luzia, MG, Brazil
Abstract:The gold–tourmaline quartz–vein deposit of Passagem de Mariana, in the southeastern part of the Quadrilátero Ferrífero, produced more than 60 tonne of gold, from the end of the 17th Century until 1954. The mine has not operated since 1985. Orebodies are veins composed of white quartz (> 60 vol.%), carbonate (ankerite), tourmaline, sericite and sulfides. Tourmaline (dravite), up to 10 vol.% of the vein, occurs as subhedral, coarse, commonly zoned crystals, and is concentrated along vein boundaries and on the edges of host rock inclusions in the veins. Tourmaline is present in all rock types in the mine, but the chemical composition of the host rocks determinates the intensity of tourmalinization, with the alteration being greater in sericitic phyllites, graphite–sericite phyllites, and calcareous rocks. The most abundant sulfide is arsenopyrite, which is normally associated with pyrite and pyrrhotite. Minor amounts of chalcopyrite, galena, löllingite, berthierite, and maldonite are present throughout the deposit. Sulfides are concentrated at veins boundary or are dispersed in the veins. Arsenopyrite is associated, most commonly, with calcareous rocks, and graphite–sericite phyllite. Pyrrhotite is usually found at the base of itabirites. Gold abundance is directly proportional to sulfide concentration. Hydrothermal alteration associated with the veins includes silicification, tourmalinization, and sulfidation. The mineralized zone is a shear zone associated with a bedding-parallel thrust fault that juxtaposes the itabirite (Lower Proterozoic Minas Supergroup) over other units. This shear zone/thrust fault extends for tens of km beyond the Passagem mine and hosts numerous gold deposits. The richest orebodies are along the itabirite footwall contact and within the graphite–sericite phyllite (Main orebody). Although many lithologic units were mineralized the graphite–sericite phyllite appears to have been most favorable for gold deposition.The area underwent three phases of deformation, D1, D2 and D3. Mineral assemblages indicate upper-greenschist to lower-amphibolite conditions of regional metamorphism. Retrograde metamorphism, characterized by chloritization of biotite and chloritization and biotitization of garnet, developed locally. The gold-bearing veins crosscut the main foliation and lithologic contacts at low angle and occur within, or are in contact with, all lithotypes. Field and laboratory data indicate that gold mineralization at Passagem de Mariana is epigenetic. Gold deposition occurred after the peak of metamorphism, within the late- to post-D2 period of deformation, which is correlated with second set of structures of Trasamazonian age of Alkmim and Marshak Alkmim, F.F., Marshak, S., 1998. Transamazonian Orogeny in the Southern São Francisco Craton Region, Minas Gerais, Brazil: evidence for Paleoproterozoic collision and collapse in the Quadrilátero Ferrífero. Precambrian Research 90, 29-58.], indicating that the gold mineralization occurred between 2.124 and 2.04 Ga. We choose to regard Passagem de Marina as an orogenic gold deposit as defined by Groves et al. Groves, D. I., Goldfarb, R.J., Gebre-Mariam, M., Hagemann, S.G., Robert, F., 1998. Orogenic gold deposits: A proposed classification in the context of their crustal distribution and relationship to other gold deposit types. Ore Geology Reviews 13, 7-27.], i.e., an epigenetic, structurally-hosted lode–gold vein system in a deformed metamorphic terrane.
Keywords:Gold  Quartz vein  Arsenopyrite  Tourmaline  Passagem de Mariana  Quadrilá  tero Ferrí  fero  Brazil
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