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A new kind of primitive chondrite, Allan Hills 85085
Authors:Edward RD Scott
Abstract:Allan Hills 85085 is a chemically and mineralogically unique chondrite whose components have suffered little metamorphism or alteration. This chondrite is unique because it has fewer and smaller chondrules (4 wt. %; mean diameter 16 μm) than any other chondrite, more metallic Fe,Ni (36%) and lithic and mineral silicate fragments (56%), and a lower abundance of troilite (2%) and volatiles. Most chondrules are cryptocrystalline or glassy and are depleted in volatiles, some small chondrules are also very depleted in refractory lithophiles. Matrix lumps (4%) partly resemble CI and CM matrices and may be foreign to the parental asteroid. Despite these differences, the components of ALH 85085 have some features common to most type 2 and the least metamorphosed type 3 chondrites: metallic Fe,Ni grains that contain 0.1–1 wt.% Cr, Si and P; Fe/(Fe + Mg) values of olivines, pyroxenes and chondrules are concentrated in the range 1–6 at.% with a few percent in the range 7–30%; porphyritic chondrules are chondritic in composition (except for their low volatile abundances). Thus the components of ALH 85085 probably have similar origins to those of components in other chondrites, and their properties largely reflect nebular, not asteroidal, processes.The bulk composition of ALH 85085 fits none of the nine groups of chondrites: it is richer in Fe (1.4 × CI levels when normalized to Si) and poorer in Na and S (0.1–0.2 × CI) than other chondrites. Low volatile concentrations are due to a low matrix abundance and loss of volatiles during or prior to chondrule formation, not to volatile loss during metamorphism. Chondrule textures imply extensive heating of chondrule melts above the liquidus, consistent with loss of volatiles from small volumes of melt during chondrule formation. The small size of chondrules is partly due to extensive fragmentation by impacts, which may have occurred on the parent asteroid or in the solar nebula. Collisions between chondrule precursor aggregates in the nebula could also be responsible for the small sizes of chondrules.Assuming that ALH 85085 is a representative sample of an asteroid, its properties lend support to models for the origins of the Earth, eucrite parent body and volatile-poor iron meteorites that invoke chondritic planetesimals depleted in volatiles. The existence of ALH 85085 and Kakangari suggests that the nine chondrite groups may provide a remarkably poor sample of the primitive chondritic material from which the asteroids formed. Certain similarities between ALH 85085 and Bencubbin and Weatherford suggest that the latter two primitive meteorites may actually be chondrites with even higher metal abundances (50–60 wt.%) and very large, partly fragmented chondrules.
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