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四川九寨沟景区钙华起源初探
引用本文:晏浩,刘再华,邓贵平,孙海龙,张金流.四川九寨沟景区钙华起源初探[J].中国岩溶,2013,32(1):15-22.
作者姓名:晏浩  刘再华  邓贵平  孙海龙  张金流
作者单位:1.中国科学院地球化学研究所/环境地球化学国家重点实验室
基金项目:国家自然科学基金项目(41172232)和中国科学院百人计划项目(2006-067)
摘    要:九寨沟风景区以绝美的景色闻名于世。钙华作为其独特景观的重要构成要素,有着重要的观赏价值和研究价值。为了弄清九寨沟钙华的起源,特别是CO2的来源,对九寨沟主要水体的水化学和碳氢氧同位素以及现代钙华的碳同位素进行了取样分析。结果发现:(1)九寨沟水体来源于大气降水的补给;(2)水体中碳酸氢根离子和钙离子浓度较低,主要来源于土壤CO2对碳酸盐岩的溶解;(3)根据碳的来源分类,九寨沟钙华应为大气成因类钙华(或表生钙华);(4)九寨沟珍珠滩钙华与碳酸氢根间较大的碳同位素分馏表明,此处生长的藻类对钙华的形成可能有重要作用。 

关 键 词:钙华起源    碳同位素    水化学    土壤CO2    四川九寨沟
收稿时间:2012/11/30 0:00:00

Origin of the tufa at Jiuzhaigou scenic spot in Sichuan
YAN Hao,LIU Zai hu,DENG Gui ping,SUN Hai long and ZHANG Jin liu.Origin of the tufa at Jiuzhaigou scenic spot in Sichuan[J].Carsologica Sinica,2013,32(1):15-22.
Authors:YAN Hao  LIU Zai hu  DENG Gui ping  SUN Hai long and ZHANG Jin liu
Institution:1.Institute of Geochemistry/State Key Laboratory of Environmental Geochemistry2.Jiuzhaigou National Scenic Area Administration, Jiuzhaigou3.Institute of Geochemistry/State Key Laboratory of Environmental Geochemistry;Hefei College
Abstract:Jiuzhaigou is well known for its unique and gorgeous scenery. As a key factor of the landscape, tufa there has high tourist value and scientific value. The hydrochemistry, stable hydrogen and oxygen iso- tope (δD and δ180) in some key water samples and stable carbon isotope (δ13C) in dissolved inorganic carbon (DIC) as well as modern tufa are examined to understand the origin of the tufa and especially the CO2 needed for the formation of the tufa at Jiuzhaigou, Sichuan. It is found that, (1) water of Jiuzhaigou is supplied by atmospheric precipitation; (2) the concentrations of HCO3-and Ca2+ in the water of Jiuzhaigou, originated from the dissolution of carbonate rock by soil CO2, are low; (3) according to the source of CO2, the tufa at Jiuzhaigou is meteor-gene or supergene (4) the large fractionation of carbon isotope between modern tufa and DIC at pearl shoal suggests that photosynthesis of algae there Played important role in the tufa deposition.
Keywords:origin of tufa  carbon isotope  hydrochemistry  soil CO2  Jiuzhaigou in Sichuan
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