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A spectrophotometric study of neodymium(III) complexation in sulfate solutions at elevated temperatures
Authors:ArtA Migdisov  VV Reukov
Institution:a Department of Earth and Planetary Sciences, McGill University, Montréal, Que., Canada H3A 2A7
b IGEM RAS, Staromonetny per. 35, Moscow 109017, Russian Federation
Abstract:The formation constants of neodymium complexes in sulfate solutions have been determined spectrophotometrically at temperatures of 30-250 °C and a pressure of 100 bars. The dominant species in the solution are NdSO4+ and Nd(SO4)2, with the latter complex being more important at higher temperature. Equilibrium constants were calculated for the following reactions:
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