A spectrophotometric study of neodymium(III) complexation in sulfate solutions at elevated temperatures |
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Authors: | ArtA Migdisov VV Reukov |
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Institution: | a Department of Earth and Planetary Sciences, McGill University, Montréal, Que., Canada H3A 2A7 b IGEM RAS, Staromonetny per. 35, Moscow 109017, Russian Federation |
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Abstract: | The formation constants of neodymium complexes in sulfate solutions have been determined spectrophotometrically at temperatures of 30-250 °C and a pressure of 100 bars. The dominant species in the solution are NdSO4+ and Nd(SO4)2−, with the latter complex being more important at higher temperature. Equilibrium constants were calculated for the following reactions: |
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