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Dissociative recombination of electrons with NO+ ions
Authors:JN Bardsley
Institution:Physics Department, University of Pittsburgh, Pittsburgh, PA 15260, U.S.A.
Abstract:Resonant scattering theory is applied to the calculation of the rate of dissociative recombination in e-NO+ collisions. For ground state ions at 300 K, the recombination rate is 4.3 × 10?7 cm3 s?1, in good agreement with the afterglow data. At higher electron temperatures, the calculated rate lies between the values measured in afterglow and trapped-ion experiments. A possible explanation of this discrepancy is offered. For vibrationally excited ions, the recombination coefficient is significantly lower than that of the ground state.
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