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长江口吴淞-浏河滨岸带沉积物AVS和SEM含量的空间分布特征
引用本文:孙玮玮,王东启,陈振楼,毕春娟,胡蓓蓓,刘耀龙,李九发,许世远.长江口吴淞-浏河滨岸带沉积物AVS和SEM含量的空间分布特征[J].地球化学,2009,38(2):140-146.
作者姓名:孙玮玮  王东启  陈振楼  毕春娟  胡蓓蓓  刘耀龙  李九发  许世远
作者单位:1. 华东师范大学,资源与环境科学学院,上海,200062
2. 华东师范大学,资源与环境科学学院,上海,200062;华东师范大学,生命科学学院,上海,200062
3. 华东师范大学,资源与环境科学学院,上海,200062;天津师范大学城市与环境科学学院,天津,300387
4. 华东师范大学河口海岸学国家重点实验室,上海,200062
基金项目:国家自然科学基金,上海市海洋局908专项,上海市重大科技攻关项目,中国博士后科学基金 
摘    要:对长江口吴淞-浏河滨岸带37个站位沉积物中酸可挥发性硫化物(AVS)和同时可提取态重金属(SEM)含量及其空间分布特征进行了研究。结果表明,SEM在37个站位沉积物中浓度范围为0.20~1.37μmol/g,平均值为0.74μmol/g;AVS的浓度范围为0.20—0.80μmol/g,平均值为0.23μmol/g;沉积物中AVS含量与总有机碳(TOC)和含水率呈显著正相关关系,而SEM分别与TOC和含水率呈显著正相关关系,与沉积物中值粒径呈显著负相关关系。依据SEM/AVS比值评价方法以及美国EPA(SEM—AVS)差值评价方法对沉积物中重金属的生物有效性的判断表明,除了B2站点无显著生物毒性外,吴淞-浏河滨岸带沉积物中重金属对水生生物均处于中等毒性水平。

关 键 词:酸可挥发性硫化物(AVS)  同时可提取态重金属(SEM)  生物有效性  沉积物  长江口

Contents and spatial distributions of AVS and SEM in Wusong-Liuhe coastal sediments in Yangtze Estuary
SUN Wei-wei,WANG Dong-qi,CHEN Zhen-lou,BI Chun-juan,HU Bei-bei,LIU Yao-long,LI Jiu-fa,XU Shi-yuan.Contents and spatial distributions of AVS and SEM in Wusong-Liuhe coastal sediments in Yangtze Estuary[J].Geochimica,2009,38(2):140-146.
Authors:SUN Wei-wei  WANG Dong-qi  CHEN Zhen-lou  BI Chun-juan  HU Bei-bei  LIU Yao-long  LI Jiu-fa  XU Shi-yuan
Institution:SUN Wei-wei1,WANG Dong-qi1,2,CHEN Zhen-lou1,BI Chun-juan1,HU Bei-bei1,3,LIU Yao-long1,LI Jiu-fa4 , XU Shi-yuan1 1.School of Resources , Environment Science,East China Normal University,Shanghai 200062,China,2.School of Life Science,3.School of Urban , Environmental Science,Tianjin Normal University,Tianjin 300387,4.State Key Laboratory of Estuarine , Coastal Research
Abstract:Acid volatile sulfides (AVS) and simultaneously extracted metals (SEM) of 57 surface sediments collected from Wusong-Liuhe coastal zone in the Yangtze Estuary were determined. The SEM contents of the surface sediments ranged from 0.20 μmol/g to 1.37μmol/g (dry weight), with an average value of 0.74 μmol/g. The AVS contents varied between 0.20 -0. 80μmol/g (dry weight), with an average being 0.23μmol/g. Sediment AVS has significant positive correlations with total organic carbon (TOC) and water content, and SEM has significant positive correlation with TOC and water content and negative correlation with medium particle size of the sediment. The ratio of SEM to AVS and the difference between SEM and AVS were used to assess the biological availability of sediment SEM content. The results show that most of the SEM in the surface sediments from the Wusong-Liuhe coastal zone in the Yangtze Estuary has moderate toxicity to the aquatic life.
Keywords:acid volatile sulfides (AVS)  simultaneously extracted metals (SEM)  biological availability  sediment  Yangtze Estuary
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