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宁芜云台山黄铁矿矿床中黄铁矿矿物的初步研究
引用本文:熊先孝,姚超美.宁芜云台山黄铁矿矿床中黄铁矿矿物的初步研究[J].化工矿产地质,1999,21(4):215-219.
作者姓名:熊先孝  姚超美
作者单位:化学矿产地质研究院
摘    要:宁芜云台山黄铁矿矿床中黄铁矿矿物以自形晶为主 ,次为他形粒状 ;黄铁矿晶胞参数为 5 .415 2 3~ 5 .41843× 10 -10 m ,晶体化学式为 (Fe0 .9968Co0 .0 0 0 6Ni0 .0 0 2 6) 1.0 0 0 0 S2 .0 597;黄铁矿红外吸收光谱主吸收峰值为 34 8cm-1,最小透过率为 30 .0 0 %~ 48.80 % ,透过率极差为 31.13~ 47.5 1;黄铁矿中Fe平均含量为 45 .44 % ,S平均含量 5 3.91% ,具有富S特征 ;Co/Ni平均值为 0 .2 1;稀土元素总量平均为2 1.84× 10 -6,具有明显负铈异常 (δCe :0 .76~ 0 .93)和负铕异常 (δEu :0 .72~ 0 .90 ) ;硫同位素组成δ3 4S为 7.0 0‰~ 2 3.0 0‰ ,黄铁矿是含矿热液以堆积、充填和交代方式形成 ,黄铁矿床为火山热水沉积矿床。

关 键 词:黄铁矿  谱学特征  晶体化学  宁芜云台山

PRELIMINARY STUDIES OF THE PYRITE MINERAL FROM YUNTAISHAN PYRITE DEPOSIT IN NANJING WUHU REGION
Xiong Xianxiao,Yao Chaomei.PRELIMINARY STUDIES OF THE PYRITE MINERAL FROM YUNTAISHAN PYRITE DEPOSIT IN NANJING WUHU REGION[J].Geology of Chemical Minerals,1999,21(4):215-219.
Authors:Xiong Xianxiao  Yao Chaomei
Institution:Geological Institute for Chemical Minerals
Abstract:The pyrite minerals from Yuntaishan pyrite deposit in Nanjing Wuhu region are recognized as euhedral and secondly, anhedral with unit cell parameter of 5.41523×10 -10 m~5.41843×10 -10 m and crystal chemical constitution of (Fe 0.9968 Co 0.0006 Ni 0.0026 ) 1.0000 S 2.0597 . The infrared absorption spectroscopy made for the mineral shows a main absorption peak of 348cm -1 , a minimum transparency degree of 30.00%~48.80% and a difference between maximum and minimum is 31.13%~47.51%. The mineral contains an average Fe of 45.44% and S of 53.91%, indicating S enrichment. Co to Ni ratio is 0.21. A total volume of REE is on average 21.84×10 -6 , with evident negative cerium ( δ Ce:0.76~0.93) and europium ( δ Eu:0.72~0.90) anomaly. Sulfur isotopic composition is 7.00‰~0.90‰. The pyrite mineral had genetic tie with concentration, filling and metasomatism of the ore bearing hydrothermal solution, and the deposits represent a sedimentary deposit caused by volcanic hydrothermal solution.
Keywords:pyrite  spectral feature  crystal chemistry  Yuntaishan of Nanjing  Wuhu region
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