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Melting temperature distribution and fractionation in the lower mantle
Authors:Eiji Ohtani
Institution:Research School of Earth Sciences, The Australian National University, Canberra, A.C.T. Australia
Abstract:The melting curve of perovskite MgSiO3 and the liquidus and solidus curves of the lower mantle were estimated from thermodynamic data and the results of experiments on phase changes and melting in silicates.The initial slope of the melting curve of perovskite MgSiO3 was obtained as dTm/dP?77 KGPa?1 at 23 GPa. The melting curve of perovskite was expressed by the Kraut-Kennedy equation as Tm(K)=917(1+29.6ΔVV0), where Tm?2900 K and P?23 GPa; and by the Simon equation, P(GPa)?23=21.2(Tm(K)2900)1.75?1].The liquidus curve of the lower mantle was estimated as Tliq ? 0.9 Tm (perovskite) and this gives the liquidus temperature Tliq=7000 ±500 K at the mantle-core boundary. The solidus curve of the lower mantle was also estimated by extrapolating the solidus curve of dry peridotite using the slope of the solidus curve of magnesiowüstite at high pressures. The solidus temperature is ~ 5000 K at the base of the lower mantle. If the temperature distribution of the mantle was 1.5 times higher than that given by the present geotherm in the early stage of the Earth's history, partial melting would have proceeded into the deep interior of the lower mantle.Estimation of the density of melts in the MgOFeOSiO2 system for lower mantle conditions indicates that the initial melt formed by partial fusion of the lower mantle would be denser than the residual solid because of high concentration of iron into the melt. Thus, the melt generated in the lower mantle would tend to move downward toward the mantle-core boundary. This downward transportation of the melt in the lower mantle might have affected the chemistry of the lower mantle, such as in the D″ layer, and the distribution of the radioactive elements between mantle and core.
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