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Assessing catchment-scale spatial and temporal patterns of groundwater and stream salinity
Authors:David L Poulsen  Craig T Simmons  Corinne Le Galle La Salle  Jim W Cox
Institution:(1) School of Chemistry, Physics and Earth Sciences, Flinders University, GPO Box 2100, Adelaide, SA, 5001, Australia;(2) CSIRO Land and Water and CRC LEME, PMB 2, Glen Osmond, SA, 5064, Australia
Abstract:Understanding catchment-scale patterns of groundwater and stream salinity are important in land- and water-salinity management. A large-scale assessment of groundwater and stream data was undertaken in the eastern Mt Lofty Ranges of South Australia using geographical information systems (GIS), regional scale hydrologic data, hydrograph separation and hydrochemical techniques. Results of the study show: (1) salts were mostly of marine origin (75%), while sulfate and bicarbonate from mineral weathering comprised most of the remainder, (2) elevated groundwater salinities and stable water isotopic compositions similar to mean rainfall indicated that plant transpiration was the primary salt accumulation mechanism, (3) key factors explaining groundwater salinity were geology and rainfall, with overall catchment salinity inversely proportional to average annual rainfall, and groundwater salinity ‘hotspots’ (EC >8 mS/cm) associated with geological formations comprising sulfidic marine siltstones and shales, (4) shallow groundwater correlated with elevated stream salinity, implying that baseflow contributed to stream salt loads, with most of the annual salt load (estimated to be 24,500 tonnes) occurring in winter when baseflow volume was highest. Salt-load analysis using stream data could be a practical, low-cost technique to rapidly target the investigation of problem areas within a catchment.
Keywords:Salinization  Salt-water/fresh-water relations  GIS  Bremer River catchment  Groundwater flow
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