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川西伟晶岩型矿床中流体包裹体的SRXRF分析
引用本文:李建康,王登红,刘善宝,应立娟,王成辉,陈栋梁.川西伟晶岩型矿床中流体包裹体的SRXRF分析[J].大地构造与成矿学,2008,32(3).
作者姓名:李建康  王登红  刘善宝  应立娟  王成辉  陈栋梁
作者单位:1. 中国地质科学院矿产资源研究所,北京,100037
2. 中国科学院高能物理研究所,北京,100049
基金项目:国家自然科学基金,中央级公益性科研院所基本科研业务费专项,中国地质调查局地质调查项目
摘    要:同步辐射X射线荧光(SRXRF)微束分析是一种无损而又具有较低检测限的技术,但在地学上的应用较少。本文尝试用SRXRF技术对川西伟晶岩型矿床——甲基卡稀有金属矿床和丹巴白云母矿床进行对比性研究。同一矿床的同类样品的SRXRF图谱形态相近,说明测试状态稳定和测试结果可信。在甲基卡矿区,相对于石英脉,锂辉石矿脉石英中的包裹体检测出较多的Fe、Mn、Co元素,并出现Ti、Rb、Ga、Zn等元素。在丹巴矿区,相对于李家工地白云母矿脉,春牛场伟晶岩检测出S及Zn,Fe的含量也较高。相对于丹巴矿床,甲基卡矿床中的包裹体相对富集金属元素,特别是Ga、Rb等。这些测试结果显示出甲基卡稀有金属矿床和丹巴白云母矿床流体组成的差异,以及矿化和非矿化伟晶岩流体的差异;说明了SRXRF是一种有效的流体包裹体测试手段,但还需要降低SRXRF探针聚焦光束光斑的大小,提高测试数据的定量化精度。

关 键 词:SRXRF  伟晶岩  甲基卡  丹巴

SRXRF MICROPROBE STUDY OF FLUID INCLUISIONS FOR PEGMATITE DEPOSITS IN WESTERN SICHUAN PROVINCE
LI Jiankang,WANG Denghong,LIU Shanbao,YING Lijuan,WANG Chenghui,CHEN Dongliang.SRXRF MICROPROBE STUDY OF FLUID INCLUISIONS FOR PEGMATITE DEPOSITS IN WESTERN SICHUAN PROVINCE[J].Geotectonica et Metallogenia,2008,32(3).
Authors:LI Jiankang  WANG Denghong  LIU Shanbao  YING Lijuan  WANG Chenghui  CHEN Dongliang
Abstract:SRXRF is an analysis technology with non-damage and low detection limit. Geologically, this technology is little applied. In this paper, SRXRF is used to detect the composition of fluid inclusions in pegmatite type deposits such as the Jiajika rare metal deposit and Danba muscovite deposit in western Sichuan Province. The SRXRF spectrums of the same type dyke in the same deposit are similar, which show the experiment is in a stable state and the spectrums are reliable. In the Jiajika deposit, the spectrum peak values of Fe, Mn, Co in the fluid inclusions of No.134 dyke are higher than those of quartz dyke. The peaks of Ti, Rb, Ga, Zn present in the fluid inclusions of No.134 spodumene dyke, but not in quartz dyke. In the Danba deposit, the spectrum peaks of S, Zn present in the fluid inclusions of the Chunniuchang pegmatite, but not in the Lijiadongdi pegmatite. The peak value of Fe in the fluid inclusions of the Chunniuchang pegmatite is higher than that of the Lijiagongdi pegmatite. Comparing with the Danba deposit, the Jiajika deposit is rich in metal elements, especially Ga and Rb. In conclusion, the experiment shows that the compositions of mineralizing fluids in the Jiajika and Danba deposit are different, and the compositions of mineralizing and non-mineralizing fluids are different, too. On the other hand, this study shows that SRXRF is an effective method to detect the compositions of fluid inclusion, and it is necessary to decrease the radius of SRXRF facula, in order to increase the precision of SRXRF.
Keywords:SRXRF
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