De-A-steroids in immature marine shales |
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| Authors: | TM Peakman P Farrimond SC Brassell JR Maxwell |
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| Abstract: | Three series of de-A-diasterenes have been observed in a variety of immature marine shales. Two of them have been identified by comparison with authentic standards and the structures of the third assigned by extrapolation. The greater complexity in the number of series compared with diasterenes indicates that the ring A degradation occurred to differing extents. The rate of C-20 diagenetic isomerisation in the de-A-diasterenes proceeds at a similar rate to that in diasterenes. Two series of B-ring monoaromatic de-A-steroid hydrocarbons have also been found. Comparison with the B-ring monoaromatic anthrasteroids indicates that the de-A-compounds are 14α(H) and 14β(H) isomers. Diagenetic isomerisation of the 14α(H) isomers to the more stable 14β(H) isomers occurs at a rate similar to that in the B-ring monoaromatic anthrasteroid series. |
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| Keywords: | black shales diagenesis of steroids isomerisation of steroids steroid hydrocarbons aromatic diagenesis isomerisation mass spectra occurrence rearranged ring A degraded synthesis |
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