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The geochemistry, mineralogy and maturity of gossans derived from volcanogenic Zn–Pb–Cu deposits of the eastern Lachlan Fold Belt, NSW, Australia
Authors:K M Scott  P M Ashley  D C Lawie
Institution:a Cooperative Research Centre for Landscape Evolution and Mineral Exploration, CSIRO Exploration and Mining, P.O. Box 136, North Ryde, NSW 1670, Australia;b Earth Sciences, University of New England, Armidale, NSW 2351, Australia;c Pasminco Exploration, G.P.O. Box 1291K, Melbourne, Vic. 3001, Australia
Abstract:The Eastern Highlands of Australia have probably been in existence since the Late Cretaceous or earlier and so there has been ample time for mature gossan profiles to form over outcropping volcanogenic Zn–Pb–Cu mineralisation in the eastern Lachlan Fold Belt. The mature gossan profiles are characterised by the upward progression from supergene sulfides to secondary sulfates, carbonates and phosphates into a Fe-oxide dominated surficial capping which may contain boxwork textures after the original sulfides (as at the Woodlawn massive sulfide deposit). However, the region has locally been subjected to severe erosion and the weathering profile over many deposits is incomplete (immature) with carbonate and phosphate minerals, especially malachite, being found in surficial material. These immature gossans contain more Cu, Pb and Zn but lower As, Sn (and probably Au) than the mature gossans. Although Pb is probably the best single pathfinder for Zn–Pb–Cu VHMS deposits of the eastern Lachlan Fold Belt, Ag, As, Au, Bi, Mo, Sb and Sn are also useful, with most of these elements able to be concentrated in substantial amounts in Fe oxides and alunite–jarosite minerals.
Keywords:gossans  volcanogenic massive sulfide deposits  eastern Australia  weathering  exploration geochemistry
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