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Organochlorine pesticides characteristics in water column of strategic drinking water sources in the Yangtze estuary
作者姓名:Qinghui  HUANG  Jianhua  LI  Jianfu  ZHAO  Ran  XU  Li  XIE
作者单位:[1]Key Laboratory of Yangtze Aquatic Environment of Ministry of Education, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China [2]State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
摘    要:Biandansha, Qingcaosha and Meimaosha sands located respectively in the upper, middle and lower reaches of the Yangtze (Changjiang River) estuary are regarded as strategic drinking water sources of Shanghai City. In the coming decade, the Qingcaosha Reservoir will first be built and gradually take the place of present water sources in the Huangpu River. However, there is little report on the occurrence of persistent organic pollutants (POPs) such as organochlorine pesticides (OCPs) in those strategic water sources. Water samples collected from those strategic water sources were filtered in-situ by Whatman GF/F filters in April 20-23, 2006. Pesticides in the filtrates were enriched on ENVI-18 solid phase extraction (SPE) tubes. OCPs eluted from SPE tubes were determined by GC-μECD method with a mixed standard solution of 20 OCPs compounds. Pentachloronitrobenzene was added as internal standard. Total concentrations of OCPs varied between 15.1 and 83.1 ng/L in water samples from Shanghai strategic water sources. A half of twenty objective OCPs compounds including DDTs were not detected. In Qingcaosha waters, there were six compounds such as a-HCH, dieldrin, endrin, endrin ketone, β-endosulfan and endosulfan sulfate. Total concentrations of these OCPs ranged from 15.1 to 31.6 ng/L and averaged 19.9 ng/L. OCPs had higher concentrations at low water tide than at high water tide, and in bottom water than in surface water. In Biandansha and Meimaosha waters, lindane (T-HCH) of 9.0 ng/L and γ-chlordane of 8.8 ng/L were found, respectively. There was no significant difference between total OCPs concentrations in surface water from Biandansha and Qingcaosha, which are much lower than those in the downstream Meimaosha waters.

关 键 词:OCPs  HCHs  DDTs  长江  河口湾  饮用水资源  有机氯

Organochlorine pesticides characteristics in water column of strategic drinking water sources in the Yangtze estuary
Qinghui HUANG Jianhua LI Jianfu ZHAO Ran XU Li XIE.Organochlorine pesticides characteristics in water column of strategic drinking water sources in the Yangtze estuary[J].Chinese Journal of Geochemistry,2006,25(B08):181-182.
Abstract:
Keywords:OCPs  HCHs  DDTs  Yangtze estuary  drinking water source
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