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Generation of unsaturated and aromatic hydrocarbons by thermal alteration of young kerogen
Authors:Ryoshi Ishiwatari  Kazuo Fukushima
Institution:Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Fukazawa, Setagaya-ku, Tokyo, Japan
Abstract:Monounsaturated, monoaromatic and polyaromatic hydrocarbons generated by artificial thermal alteration of young marine (Tanner basin, offshore California) kerogen were studied by computerized GC-MS. Their relative amounts changed with temperature (150–410°C) and time (5–120 hr) of heating as follows: Monounsaturates → Monoaromatics → Polyaromatics. Distribution of alkyl homologs of phenanthrene also changed with increasing degree of thermal alteration. These results are in agreement with those observed for crude oils and shales.
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