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2-萘酚吸附树脂热解和燃烧特性的研究
引用本文:周宏仓,金保升,仲兆平,肖睿,黄亚继.2-萘酚吸附树脂热解和燃烧特性的研究[J].南京气象学院学报,2006,29(4):435-439.
作者姓名:周宏仓  金保升  仲兆平  肖睿  黄亚继
作者单位:1. 南京信息工程大学,环境科学与工程系,江苏,南京,210044
2. 东南大学,洁净煤发电与燃烧技术教育部重点实验室,江苏,南京,210096
基金项目:南京信息工程大学校科研和教改项目
摘    要:利用热重-差热分析仪对染料化工企业产生的2-萘酚吸附树脂在4种不同气氛下的热重(TG)和微分热重(DTG)曲线进行研究。试验结果表明:2-萘酚吸附树脂在高温、氧化条件下不稳定,易于分解,其热分解失重率受气氛变化的影响较大。提出了2-萘酚吸附树脂热解和燃烧机理,给出了热解反应动力学参数和模型。

关 键 词:2-萘酚吸附树脂  热解特性  燃烧特性  动力学参数  热重分析仪
文章编号:1000-2022(2006)04-0435-05
收稿时间:06 23 2005 12:00AM
修稿时间:2005-06-232005-07-11

Study on Pyrolysis and Combustion Characters of 2-Naphthol Adsorption Resin
ZHOU Hong-cang,JIN Bao-sheng,ZHONG Zhao-ping,XIAO Rui,HUANG Ya-ji.Study on Pyrolysis and Combustion Characters of 2-Naphthol Adsorption Resin[J].Journal of Nanjing Institute of Meteorology,2006,29(4):435-439.
Authors:ZHOU Hong-cang  JIN Bao-sheng  ZHONG Zhao-ping  XIAO Rui  HUANG Ya-ji
Institution:1. Department of Environmental Science and Engineering, NUIST, Nanjing 210044, China; 2. Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, SEU, Nanjing 210096, China
Abstract:To realize the incineration of 2-naphthol adsorption resin from dye chemical plants,the performance of the pyrolysis and combustion characters of 2-naphthol adsorption resin has been tested on the TGDTA 92 thermogravimetric(TG) analyzer at four different atmospheres.This apparatus can perform experiments such as TG and differential TG(DTG) analyses at the same time.The experimental results indicate that 2-naphthol adsorption resin is unstable and is easy to decompose at high temperature with the presence of oxygen.The weight loss rate of 2-naphthol adsorption resin was affected by the oxygen content of the carried gas.A pyrolysis and combustion mechanism of 2-naphthol adsorption resin was presented.The pyrolysis kinetics parameters of 2-naphthol adsorption resin were obtained and a proper kinetics model was proposed.
Keywords:2-naphthol adsorption resin  pyrolysis character  combustion character  kinetic parameters  thermogravimetric analyzer
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