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Degradation of petroleum contaminants in oil
作者姓名:Yanying  SUN  Fei  LIU  Honghan  CHEN  Wei  HE
作者单位:Beijing Key Laboratory of Water Resources and Environmental Engineering, China University of Geosciences, Beijing 100083, China
摘    要:The treatment of diesel-contaminated soil with hydrogen peroxide oxidation is investigated in this paper. The factors influencing reactions such as initial oil content, H2O2 dosage, pH-value, catalyst and so on are studied. The results indicate that it is feasible to remediate diesel-contaminated soil by adding oxidant directly at room temperature because of higher absolute removal content although the degradation efficiency is low for the contaminated soil of 1%, 2% and 5% initial oil content. The more the H2O2 dosage, the better the degradation efficiency; it is economical and efficient to add 4 mL H2O2 to 10 g diesel-contaminated soil (2% or so) directly in-situ chemical oxidation (ICO). For the contaminated soil of 5% initial oil content, when pH-value is 5-8 and H202 dosage is 20 mL, the removal efficiency reaches more than 96%; when pH-value is 1-3 and volume ratios of H2O2 to Fe^2+ are 1 : 1, 2:2, the degradation efficiencies are all very high (i.e., 86%-88% or so). It can be concluded that the degradation efficiencies are comparative when adding 1 mL or 2 mL H2O2 of Fenton Reagent or adding 4 mL of H2O2 only to 10 g diesel-contaminated soil.

关 键 词:土壤污染  石油  降解作用  催化剂

Degradation of petroleum contaminants in oil
Yanying SUN Fei LIU Honghan CHEN Wei HE.Degradation of petroleum contaminants in oil[J].Chinese Journal of Geochemistry,2006,25(B08):126-127.
Abstract:
Keywords:chemical oxidation  petroleum contaminant  diesel-contaminated soil  hydrogen peroxide  Fenton Reagent
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