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Cl-37 in the Dead Sea system---preliminary results
Authors:Mariana Stiller  Arie Nissenbaum  Ronald S Kaufmann  Austin Long
Institution:aWeizmann Institute of Science, 76100 Rehovot, Israel;bDepartment of Geology, Northern Illinois University, DeKalb, IL 60511, USA;cDepartment of Geosciences, University of Arizona, Tucson, AZ 85721, USA
Abstract:This study presents the first set of δ measurements in the Dead Sea environment. δ values for the meromictic (long term stratified) Dead Sea water column prior to its complete overturn in 1979 were −0.47‰ SMOC for the UWM (Upper Water Mass) and +0.55‰ SMOC for the LWM (Lower Water Mass). The δ values for the pre-overturn Dead Sea cannot be explained by the prevailing model on the evolution of the Dead Sea during the last few centuries and require corroboration by more measurements. The 1979 overturn wiped out almost completely the isotopic differences between the UWM and LWM. Even so, Cl isotope data could be used to decipher physical processes related to the overturn such as incomplete homogenization of the deep water mass. Inputs into the lake, comprising freshwaters (springs and the Jordan River) and saline springs gave a range of −0.37‰ to +1.0‰ with the freshwater sources being more enriched in δ . Based on the δ measurements of the End-Brine (the effluent from Dead Sea evaporation ponds) and of recent Dead Sea halite, the Cl isotopic composition of the originating brines have been estimated. They gave a narrow isotopic spread, +0.01‰ and +0.07‰ and fall within the same range with Dead Sea pore water (+0.13‰) and with the post-overturn Dead Sea (−0.03‰ and +0.16‰). Rock salt from Mount Sdom gave a value of −0.59‰ indicating its formation at the last stages of halite deposition from evaporating sea water. The hypersaline En Ashlag spring gave a depleted δ value of −0.32‰, corresponding to a residual brine formed in the very latest stages (including bishofite deposition) of seawater evaporation.
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