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Nitrogen Sulfide In Comets Hyakutake (C/1996 B2) And Hale–Bopp (C/1995 O1)
Authors:Canaves  Marcus V  De Almeida  Amaury A  Boice  Daniel C  Sanzovo  Gilberto C
Institution:1.Department of Astronomy, Institute of Astronomy, Geophysics and Atmospheric Sciences, University of S?o Paulo, Main Campus, Rua do Mat?o, 1226, CEP 05508-0900, S?o Paulo, S?o Paulo, Brazil
;2.Department of Space Science, Instrumentation and Space Research Division, Southwest Research Institute, P.O. Drawer 28510, San Antonio, Texas, 78228-0510, USA
;3.Laboratory of Molecular Astrophysics, Department of Physics, State, University of Londrina, Perobal, CEP 86051-970, Londrina, Paraná, Brazil
;
Abstract:The chemistry of both nitrogen and sulfur presents interesting problems in comets.In this paper, we use a model of cometary comae with gas-phase chemical kineticsand gas dynamics to predict molecular abundances in the inner coma region for twoof the brightest comets in the past 20 years, Hyakutake (C/1996 B2) and Hale–Bopp(C/1995 O1). In this progress report we concentrate on the gas-phase chemistry of thenitrogen sulfide (NS) radical at a heliocentric distance of 1 AU to study the abundanceof NS using a detailed photo and chemical reaction network with over 100 species andabout 1000 reactions. The results are compared with recent observations of CometHale–Bopp and reveal that conventional gas-phase reactions schemes do not produceNS in sufficient quantities to explain the observations. We plan to continue therefinement of the model to improve agreement with observational constraints.
Keywords:Abundance  comet C/1995 O1 Hale–  Bopp  comet C/1996 B2 Hyakutake  cometary comae  nitrogen sulfide
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