Uranium-series disequilibrium in tuffs from Yucca Mountain,Nevada, as evidence of pore-fluid flow over the last million years |
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| Institution: | 1. Atomic Energy of Canada Limited, Whiteshell Laboratories, Pinawa, MB R0E 1L0 Canada;2. Pacific Western Technologies Ltd., c/o U.S. Geological Survey, Denver Federal Center, MS 963, Box 25046, Denver, CO 80225, USA;1. College of Earth Sciences, Jilin University, Changchun, 130061, China;2. Key Laboratory for Oil Shale and Paragenetic Energy Minerals, Jilin University, Changchun, 130061, China;3. Department of Earth and Planetary Sciences and MQMarine Research Centre, Macquarie University, North Ryde, NSW, 2109, Australia;4. Center of Oil and Gas Resources Survey, China Geological Survey, Beijing, 100083, China;1. Department of Mechanical Engineering, The Hong Kong Polytechnic University, Kowloon, Hong Kong;2. The Hong Kong Polytechnic University, Shenzhen Research Institute, Shenzhen, PR China;3. Institute of Fluid Engineering, Zhejiang University, Hangzhou, Zhejiang, PR China;4. Department of Atmospheric Sciences, Zhejiang University, Hangzhou, Zhejiang, PR China;1. Geological Survey of Finland, P.O. Box 96, FI-02151 Espoo, Finland;2. Geological Survey of Finland, P.O. Box 1237, FI-70211 Kuopio, Finland;3. Pampalo Mine, Pampalontie 11, FI-82967 Hattu, Finland;4. Department of Geosciences, Swedish Museum of Natural History, Box 50 007, SE-104 05 Stockholm, Sweden;1. AORC, Sungkyunkwan University, Suwon 16419, South Korea;2. Department of Mathematics Education, Sungkyunkwan University, Seoul 03063, South Korea;3. Department of Mathematics, Sungkyunkwan University, Suwon 16419, South Korea;1. Laboratory of Clinical and Experimental Toxicology, Poison Control Centre, Toxicology Unit, Maugeri Clinical Scientific Institutes S.p.A.-BS, IRCCS Pavia, Pavia Italy;2. Department of Veterinary Medicine (DIMEVET), Università degli Studi di Milano, Milano, Italy |
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| Abstract: | Samples of tuff from boreholes drilled into fault zones in the Exploratory Studies Facility (ESF) and relatively unfractured rock of the Cross Drift tunnels, at Yucca Mountain, Nevada, have been analysed by U-series methods. This work is part of a project to verify the finding of fast flow-paths through the tuff to ESF level, indicated by the presence of ‘bomb’ 36Cl in pore fluids. Secular radioactive equilibrium in the U decay series, (i.e. when the radioactivity ratios 234U/238U, 230Th /234U and 226Ra/230Th all equal 1.00) might be expected if the tuff samples have not experienced radionuclide loss due to rock-water interaction occurring within the last million years. However, most fractured and unfractured samples were found to have a small deficiency of 234U (weighted mean 234U/238U=0.95±0.01) and a small excess of 230Th (weighted mean 230Th/234U 1.10±0.02). The 226Ra/230Th ratios are close to secular equilibrium (weighted mean=0.94±0.07). These data indicate that 234U has been removed from the rock samples in the last ～350 ka, probably by pore fluids. Within the precision of the measurement, it would appear that 226Ra has not been mobilized and removed from the tuff, although there may be some localised 226Ra redistribution as suggested by a few ratio values that are significantly different from 1.0. Because both fractured and unfractured tuffs show approximately the same deficiency of 234U, this indicates that pore fluids are moving equally through fractured and unfractured rock. More importantly, fractured rock appears not to be a dominant pathway for groundwater flow (otherwise the ratio would be more strongly affected and the Th and Ra isotopic ratios would likely also show disequilibrium). Application of a simple mass-balance model suggests that surface infiltration rate is over an order of magnitude greater than the rate indicated by other infiltration models and that residence time of pore fluids at ESF level is about 400 a. Processes of U sorption, precipitation and re-solution are believed to be occurring and would account for these anomalous results but have not been included in the model. Despite the difficulties, the U-series data suggest that fractured rock, specifically the Sundance and Drill Hole Wash faults, are not preferred flow paths for groundwater flowing through the Topopah Spring tuff and, by implication, rapid-flow, within 50 a, from the surface to the level of the ESF is improbable. |
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