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杭州主城区O3与前体物浓度变化特征
引用本文:洪盛茂,焦荔,何曦,孙鸿良,徐鸿,杨乐,何纪平.杭州主城区O3与前体物浓度变化特征[J].气候与环境研究,2009,14(6):657-664.
作者姓名:洪盛茂  焦荔  何曦  孙鸿良  徐鸿  杨乐  何纪平
作者单位:杭州市环境监测中心站,杭州,310007
基金项目:杭州市科技局重点项目20092113A05 
摘    要:利用2004~2006年杭州主城区环境空气监测资料,研究了O_3、NO_2和CO浓度的分布特征和时间变化规律,结果表明,杭州主城区3年的O_3、NO_2、CO的年均浓度都不大,分别为40、60、1400μg·m~(-3).四季中O_3、NO_2和CO浓度相差较大,O_3是夏季高冬季低,NO_2和CO则是秋季较高,夏季较低.O_3、NO_2和CO浓度日变化也很明显,其中O_3是单峰形态,NO_2和CO为双峰形态.不同天气条件下O_3与烃类的关系研究表明,晴天时烃类浓度减少,O_3浓度明显增加;阴天时O_3浓度较低,烃类浓度较高,它们的变化不大.白天和夜晚不同风速时O_3、C_2-C_(12)的浓度变化不同,白天风速增大时C_2-C_(12)浓度减小,O_3浓度增加;晚上无此变化.

关 键 词:前体物  天气条件

Characteristics of O3 and Precursors Concentrations in Hangzhou Urban Areas
HONG Shengmao,JIAO Li,HE Xi,SUN Hongliang,XU Hong,YANG Le and HE Jiping.Characteristics of O3 and Precursors Concentrations in Hangzhou Urban Areas[J].Climatic and Environmental Research,2009,14(6):657-664.
Authors:HONG Shengmao  JIAO Li  HE Xi  SUN Hongliang  XU Hong  YANG Le and HE Jiping
Abstract:Based on the air monitoring data in Hangzhou urban areas from 2004 to 2006, the concentrations of O_3 , NO_2 , CO, and their temporal variation characteristics were analyzed.The results showed that all the annual mean concentrations of O_3 , NO_2, and CO were low in the three years, which were 40, 60, and 1400 μg · m~(-3) , respec-tively. The concentrations of O_3 , NO_2 , and CO were different among seasons, O_3 concentration was the highest in summer and the lowest in winter, while both NO_2 and CO concentrations were higher in winter and lower m summer. The diurnal variations of the concentrations of O_3 , NO_2 , and CO were obvious, the diurnal variations of O_3 concentrations showed one peak, while the others had two peaks.The relationship between O_3 and hydrocarbons concentration in different weather conditions showed that O_3 concentration increased significantly and hydrocarbons reduced during cloudless days, but during cloudy days O_3 concentration was lower and hydrocarbons concentrations were higher, and their concentrations changed little In the daytime and nighttime, O_3 and C_2-C_(12) hydrocarbons concentrations changed with different wind velocity. In the daytime, the C_2-C_(12) hydrocarbons concentrations reduced with the increase of wind speed, and O_3 was exactly opposite.The similar situation was not found in the nighttime.
Keywords:C_2-C_(12)  precursor  C_2- C_(12) hydrocarbons  weather condition
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