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Major element distribution in Archean banded iron formation (BIF): influence of metamorphic differentiation
Authors:N KATSUTA  I SHIMIZU  H HELMSTAEDT  M TAKANO  S KAWAKAMI  M KUMAZAWA
Institution:1. Faculty of Education, Gifu University, 1‐1 Yanagido, Gifu 501‐1193, Japan;2. Department of Earth and Planetary Science, Graduate School of Science, University of Tokyo, 7‐3‐1 Hongo, Bunkyo‐ku, Tokyo 113‐0033, Japan (ichiko@eps.s.u‐tokyo.ac.jp);3. Department of Geological Sciences, Queen’s University, Kingston, Ontario K7L 3N6, Canada;4. Graduate School of Environmental Studies, Nagoya University, Furo‐cho, Chikusa‐ku, Nagoya 464‐8601, Japan
Abstract:The Archean (2.8 Ga) Banded Iron Formation (BIF) of the Bell Lake region of Yellowknife greenstone belt, Canada is recrystallized to metamorphic assemblages of the amphibolite facies. This BIF is characterized by centimetre‐scale Fe‐rich and Si‐rich mesobands. In the Si‐rich mesobands, thin layers of magnetite microbands are developed in a quartz matrix. The Fe‐rich mesobands are composed mainly of Ca‐amphibole (hornblende), Fe–Mg amphibole (grunerite), and magnetite. The metamorphic foliation locally cuts across the mesoband boundaries, indicating the mesobanding was formed prior to peak metamorphism. Variations in mineral modal proportions between Fe‐rich mesobands and microbands are diagnostic of depositional compositional differences between beds. Micro‐X‐ray fluorescence imaging reveals metamorphic differentiation within Fe‐rich mesobands, with segregation of Fe–Mg amphibole, and the incompatible element Mn is concentrated at the margins of the Fe‐rich mesobands during the amphibole‐forming reactions. Ti was relatively immobile during metamorphic segregation and its distribution provides a record of the original structures in the Fe‐rich mesobands.
Keywords:amphibole  Archean  banded iron formation (BIF)  compositional banding  scanning X‐ray analytical microscope (SXAM)  titanium
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