The relationship between fluid flow and mineral weathering in heterogeneous unsaturated porous media: A physical and geochemical characterization of a waste-rock pile |
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| Institution: | 1. CSIRO Mineral Resources, Urrbrae, SA 5064, Australia;2. College of Science and Engineering, Flinders University, Bedford Park, SA 5042, Australia;3. School of Resources and Environmental Engineering, Wuhan University of Technology, Hubei 430070, China;4. Future Industries Institute, University of South Australia, Mawson Lakes, SA 5095, Australia;5. Environmental Geochemistry International, Balmain, NSW 2041, Australia;6. CSIRO Mineral Resources, Clayton South, VIC 3169, Australia;7. Blue Minerals Consultancy, Wattle Grove TAS 7109, Australia;1. Department of Civil and Geological Engineering, University of Saskatchewan, Saskatoon, SK, Canada;2. The State Key Laboratory of Soil Erosion and Dryland Farming on Loess Plateau, ISWC, Northwest A&F University, Yangling, Shaanxi, China;1. Department of Petroleum and Geosystems Engineering, University of Texas at Austin, Austin, TX, USA;2. Department of Physics and Department of Earth and Environmental Science, Wright State University, Dayton, OH, USA |
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| Abstract: | The relationships between factors that control subsurface flow and the timing, duration, and intensity of acidity generation and leaching of metals from waste-rock dumps are investigated. A 12 m high waste-rock pile that had been constructed in 1994 at Key Lake, Saskatchewan, Canada was disassembled, sampled and characterized in 2000. Physical properties that control water flow were characterized by measuring soil–water suction, volumetric water content, and the grain-size distribution at 60 randomized sites within the pile. Grain-size distribution was also measured at an additional 20 grid locations within the pile. Paste pH, pore-water geochemistry, mineralogy, and water-soluble extractions were used to investigate geochemical processes and sulfide oxidation at each of the 20 grid locations. A field-based soil–water characteristic curve could not be developed from the spatially variable and hysteretic field data; consequently, the grain-size distribution was used as a relative measure of subsurface flow and of the tendency to contain water under unsaturated conditions. The geochemical characterization demonstrated that marcasite underwent preferential weathering relative to pyrite and chalcopyrite, that dolomite was the main buffering carbonate mineral, and that gypsum, jarosite, and Fe oxyhydroxides were the main secondary (supergene) minerals. The pore waters contained up to 78,000 mg L?1 SO4, 690 mg L?1 Ni and 1400 mg L?1 U (800, 11.7 and 6 mM, respectively), suggesting that significant weathering had occurred. The pore water chemistry varied considerably between sampling sites. However, neither a correlation of pore-water chemistry with grain-size distribution nor a spatial relationship within the sampled grid was discernible. |
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