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New Insights into Crustal Contributions to Large-volume Rhyolite Generation in the Mid-Tertiary Sierra Madre Occidental Province, Mexico, Revealed by U Pb Geochronology |
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| Authors: | Bryan Scott E; Ferrari Luca; Reiners Peter W; Allen Charlotte M; Petrone Chiara M; Ramos-Rosique Aldo; Campbell Ian H |
| Institution: | 1Department of Geology & Geophysics, Yale University, PO Box 208109, New Haven, CT 06520-8109, USA 2Centro de Geociencias, Universidad Nacional Autónoma de Mexico, Campus Juriquilla, Queretaro 76230, Mexico 3Research School of Earth Sciences, Australian National University, Canberra, A.C.T. 0200, Australia 4C.N.R.–Istituto Geoscience e Georisorse, U.O. Firenze, Via G. La Pira 4, 50121 Firenze, Italy 5Centre for Earth and Environmental Science Research, Kingston University, Penhryn Road, Kingston Upon Thames KT1 2EE, UK |
| Abstract: | Voluminous ( 3·9 x 105 km3), prolonged ( 18 Myr) explosivesilicic volcanism makes the mid-Tertiary Sierra Madre Occidentalprovince of Mexico one of the largest intact silicic volcanicprovinces known. Previous models have proposed an assimilation–fractionalcrystallization origin for the rhyolites involving closed-systemfractional crystallization from crustally contaminated andesiticparental magmas, with <20% crustal contributions. The lackof isotopic variation among the lower crustal xenoliths inferredto represent the crustal contaminants and coeval Sierra MadreOccidental rhyolite and basaltic andesite to andesite volcanicrocks has constrained interpretations for larger crustal contributions.Here, we use zircon age populations as probes to assess crustalinvolvement in Sierra Madre Occidental silicic magmatism. Laserablation-inductively coupled plasma-mass spectrometry analysesof zircons from rhyolitic ignimbrites from the northeasternand southwestern sectors of the province yield U–Pb agesthat show significant age discrepancies of 1–4 Myr comparedwith previously determined K/Ar and 40Ar/39Ar ages from thesame ignimbrites; the age differences are greater than the errorsattributable to analytical uncertainty. Zircon xenocrysts withnew overgrowths in the Late Eocene to earliest Oligocene rhyoliteignimbrites from the northeastern sector provide direct evidencefor some involvement of Proterozoic crustal materials, and,potentially more importantly, the derivation of zircon fromMesozoic and Eocene age, isotopically primitive, subduction-relatedigneous basement. The youngest rhyolitic ignimbrites from thesouthwestern sector show even stronger evidence for inheritancein the age spectra, but lack old inherited zircon (i.e. Eoceneor older). Instead, these Early Miocene ignimbrites are dominatedby antecrystic zircons, representing >33 to 100% of the datedpopulation; most antecrysts range in age between 20 and 32 Ma.A sub-population of the antecrystic zircons is chemically distinctin terms of their high U (>1000 ppm to 1·3 wt %) andheavy REE contents; these are not present in the Oligocene ignimbritesin the northeastern sector of the Sierra Madre Occidental. Thecombination of antecryst zircon U–Pb ages and chemistrysuggests that much of the zircon in the youngest rhyolites wasderived by remelting of partially molten to solidified igneousrocks formed during preceding phases of Sierra Madre Occidentalvolcanism. Strong Zr undersaturation, and estimations for veryrapid dissolution rates of entrained zircons, preclude coevalmafic magmas being parental to the rhyolite magmas by a processof lower crustal assimilation followed by closed-system crystalfractionation as interpreted in previous studies of the SierraMadre Occidental rhyolites. Mafic magmas were more probablyimportant in providing a long-lived heat and material flux intothe crust, resulting in the remelting and recycling of oldercrust and newly formed igneous materials related to Sierra MadreOccidental magmatism. KEY WORDS: ignimbrite; rhyolite; Sierra Madre Occidental; Tertiary; U–Pb geochronology; zircon; antecryst; crustal melting |
| Keywords: | : ignimbrite rhyolite Sierra Madre Occidental Tertiary U-Pb geochronology zircon antecryst crustal melting |
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