Spectroscopic Studies on Astrophysically Interesting TaO TaS, ZrS and SiO+ Molecules |
| |
| Authors: | RR Reddy Y Nazeer Ahammed B Sasikala Devi K Rama Gopal P Abdul Azeem TVR Rao |
| |
| Institution: | (1) Department of Physics, Sri Krishnadevaraya University, Anantapur –, 515 003 Andhra Pradesh, India |
| |
| Abstract: | The true experimental potential energy curves for the electronic ground states of astrophysically important TaO, TaS, ZrS
and SiO+molecules are constructed by using the Rydberg–Klein–Rees method as modified by Vanderslice et al. The ground state dissociation
energies are determined by curve fitting techniques using the five parameters Hulburt-Hirschfelder (H-H) function. The estimated
dissociation energies are 8.19 ± 0.17, 6.9 ±0.14, 5.89 ± 0.12 and 5.75 ± 0.12 eVfor TaO, TaS, ZrS and SiO+ respectively. These values are in good agreement with the literature values. The r-centriods and Franck–Condon factors (FC
Factors) for the bands of K
2
φ
5/2
- X
2
Δ
3/2
(K-X) system of TaO, A-X
2 Δ (A-X) and B-X
2 Δ (B-X)systems of TaS, B
1 Π - X1 Σ+
(B-X) system of ZrS and B
2Σ+ - X2 Σ+
(B-X) and A
2 Π - X2 Σ+
(A-X)systems of SiO+ molecules have been calculated. The Franck–Condon factors (FC factors) are evaluated by the approximate analytical methods
of Jarmain and Fraser. The absence of the bands of these systems is explained.
This revised version was published online in July 2006 with corrections to the Cover Date. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
