| Stable Carbon Isotopic Compositions of Methylated-MTTC in Crude Oils from Saline Lacustrine Depositional Environment: Source Implications |
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| 作者姓名： | LU Hong HOU Linhui CHEN Tengshui PENG Ping’an SHENG Guoying |
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| 作者单位： | State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640;State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640;State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640;State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640;State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640 |
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| 基金项目： | This work was supported mainly by the State “973” Project (2006CB701404), CAS Project (KZCX2-YW-114-1) and NSFC Project (40402013). |
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| 摘 要： | Significantly high abundant methyl-MethylTrimethylTridecylChromans (MTTCs) have been detected in aromatic hydrocarbon fractions in crude oils from the Jizhong Depression and Jianghan Basin. The distribution of these compounds is dominated by methyl-MTTC and dimethyl-MTTC series, which indicate diagenetic products of a hypersaline depositional environment in the early stage and show a low degree of methylation. The occurrence of significantly high abundant methyl-MTTC depends mainly on good preservation conditions with a strongly reductive, hypersaline and water-columned depositional environment and subsequent non-intensive diagenetic transformations. The stable carbon isotopic compositions of the methyl-MTTCs and dimethyl-MTTCs in two samples are far different from the stable carbon isotopic composition of C30 hopane of apparent bacteria biogenesis (up to 4.11‰ and 5.75‰, respectively). This obviously demonstrates that the methyl-MTTC and dimethyl-MTTCs cannot be of bacteria origin, which is different from the previous point of view about non-photosynthetic bacteria products or possible bacteria-reworked products. On the contrary, the stable carbon isotopic compositions of methyl-MTTC and dimethyl-MTTCs in the two samples were similar to that of the same carbon-numbered n-alkanes (nC27-nC28-nC29), which indicates that they share the same source origin. Especially in the crude oil from the Zhao61 well, stable carbon isotopic compositions are also similar to that of the same carbon-numbered steranes with ααα-20R isomer (mostly less than 0.4‰). In consideration of the results of previous studies on saline lake ecological sedimentation, the authors hold that the methyl-MTTC and dimethyl-MTTCs in the saline lake sediments should be of algal biogenesis origin.
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| 关 键 词： | chroman tocopherol methylated-MTTC stable carbon isotopic composition algae biogenesis saline lacustrine facies |
| 收稿时间： | 2007/8/24 0:00:00 |
| 修稿时间： | 2007/9/25 0:00:00 |
Stable Carbon Isotopic Compositions of Methylated-MTTC in Crude Oils from Saline Lacustrine Depositional Environment: Source Implications |
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| Authors: | LU Hong HOU Linhui CHEN Tengshui PENG Ping'an SHENG Guoying |
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| Abstract: | Abstract: Significantly high abundant methyl‐MethylTrimethylTridecylChromans (MTTCs) have been detected in aromatic hydrocarbon fractions in crude oils from the Jizhong Depression and Jianghan Basin. The distribution of these compounds is dominated by methyl‐MTTC and dimethyl‐MTTC series, which indicate diagenetic products of a hypersaline depositional environment in the early stage and show a low degree of methylation. The occurrence of significantly high abundant methyl‐MTTC depends mainly on good preservation conditions with a strongly reductive, hypersaline and water‐columned depositional environment and subsequent non‐intensive diagenetic transformations. The stable carbon isotopic compositions of the methyl‐MTTCs and dimethyl‐MTTCs in two samples are far different from the stable carbon isotopic composition of C30 hopane of apparent bacteria biogenesis (up to 4.11%a? and 5.75%a?, respectively). This obviously demonstrates that the methyl‐MTTC and dimethyl‐MTTCs cannot be of bacteria origin, which is different from the previous point of view about non‐photosynthetic bacteria products or possible bacteria‐reworked products. On the contrary, the stable carbon isotopic compositions of methyl‐MTTC and dimethyl‐MTTCs in the two samples were similar to that of the same carbon‐numbered n‐alkanes (nC27‐nC28‐nC29), which indicates that they share the same source origin. Especially in the crude oil from the Zhao61 well, stable carbon isotopic compositions are also similar to that of the same carbon‐numbered steranes with ααα‐20R isomer (mostly less than 0.4%). In consideration of the results of previous studies on saline lake ecological sedimentation, the authors hold that the methyl‐MTTC and dimethyl‐MTTCs in the saline lake sediments should be of algal biogenesis origin. |
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| Keywords: | chroman tocopherol methylated-MTTC stable carbon isotopic composition algae biogenesis saline lacustrine facies |
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