Geochemistry of hydrothermal deposits from Loihi submarine volcano,Hawaii |
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| Authors: | Eric H De Carlo Gary M McMurtry Hsueh-Wen Yeh |
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| Institution: | Hawaii Institute of Geophysics, University of Hawaii, Honolulu, HI 96822 U.S.A. |
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| Abstract: | Dredging across the northeast rim of the summit crater of Loihi Seamount recovered several morphologically similar but chemically and mineralogically distinct hydrothermal deposits encrusting the surface of fresh pillow lava talus. The multicolored deposits suggest a precipitation sequence that may be controlled by an oxidation-reduction gradient in which smectite ranging in composition from Fe-montmorillonite to nontronite has precipitated along with iron oxide under slightly reducing conditions. This deposition was apparently followed by amorphous iron oxide and silica precipitation, possibly under more oxic conditions. Oxygen isotope geothermometry indicates formation temperatures in the range of 31–57°C for the Loihi smectites. Trace element enrichments appear to be positively correlated with the isotopic formation temperature of the smectite, suggesting either increased trace element solubility within the higher-temperature vent fluids or increased smectite and iron oxide scavenging with increased precipitation rates. The trace element abundances further suggest the presence of polymetallic sulfides that either are directly associated with the smectites as amorphous phases or occur beneath these deposits in the volcanic pile of the seamount. |
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| Keywords: | Author to whom correspondence should be sent |
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