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The evolution of early precambrian crustal rocks at Isua,West Greenland — Geochemical and isotopic evidence
Authors:S Moorbath  RK O&#x;Nions  RJ Pankhurst
Institution:Department of Geology and Mineralogy, Oxford University, Oxford Great Britain
Abstract:Petrographic and chemical evidence suggests that boulders from a conglomeratic unit in the Isua supracrustal succession were derived by the erosion of an acid volcanogenic sediment. Six samples of the boulders and surrounding matrix yield a Rb-Sr whole rock isochron with a slope corresponding to an age of 3860 ± 240 m.y. (2 sigma error), but consideration of the initial87Sr/86Sr ratio constrains the possible age of formation of 3710 ± 900 m.y. This is in general agreement with a published Pb/Pb age of 3760 ± 70 m.y. on Isua banded ironstones.Pb isotope compositions as well as highly fractionated, heavy element depleted, rare earth element abundance patterns for the boulders suggest that their igneous precursors were derived from a source region with a similar geochemical history to that of some components of the 3700–3800 m.y. old Ami?tsoq gneisses, involving fractionation of garnet during their evolution.A Pb/Pb whole-rock isochron for Ami?tsoq gneisses from Isua yields an age of 3800 ± 120 m.y. (2σ), in good agreement with previously published Rb-Sr age data on the same rocks. The rock leads are highly unradiogenic and demonstrate substantial U depletion at least 3800 ± 120 m.y. ago. A two-stage model for the U-Pb system yields an average238U/204Pb (μ1) value of 9.3 ± 0.2 for the source region, which is significantly different from the published value of 9.9 ± 0.1 for the Isua iron formation. This indicates the existence of U-Pb heterogeneities between the source regions of plutonic and supracrustal rocks by about 3700–3800 m.y. ago. Attempts to apply U-Pb whole-rock dating to the Ami?tsoq gneisses were unsuccessful because of geologically recent U loss, possibly due to groundwater leaching.A Rb-Sr whole-rock isochron on a suite of Ami?tsoq gneiss samples from a different locality in the Isua region has yielded an age of 3780 ± 130 m.y.In contrast to the Godthaab area, there is no geochronological evidence at Isua for major rock-producing or tectonothermal events after about 3700 m.y. ago. The entire gneiss-supracrustal system developed within the approximate interval 3900–3700 m.y. ago.
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