| 开链冠醚2，6-二(8'-喹啉氧甲基)-4-甲基-苯甲醚及其Ag( Ⅰ )、Cu( Ⅱ )、Ni( Ⅱ )配合物的合成与性质研究 |
| |
| 引用本文： | 张前前,季振平,萧文锦,吴成泰.开链冠醚2，6-二(8''''-喹啉氧甲基)-4-甲基-苯甲醚及其Ag( Ⅰ )、Cu( Ⅱ )、Ni( Ⅱ )配合物的合成与性质研究[J].中国海洋大学学报(自然科学版),2001,31(3):420-424. |
| |
| 作者姓名： | 张前前 季振平 萧文锦 吴成泰 |
| |
| 作者单位： | 1. 青岛海洋大学化学化工学院,
2. 武汉大学化学与环境科学学院, |
| |
| 摘 要： | 设计合成一种尚未见文献报道的酚醚型双臂开链冠醚化合物L(L=2,6-二(8’-喹啉氧甲基)-4-甲基-苯甲醚)，经元素分析、IR、1HNMR、MS等方法确定了其组成和结构。其Ag(Ⅰ)、Cu(Ⅱ)、Ni(Ⅱ)固体配合物的元素分析结果表明金属离子不同，则其配合物的配位比(M∶L)不同，Ag(Ⅰ)配合物为1∶1，Cu(Ⅱ)、Ni(Ⅱ)配合物为2∶3。并运用热重-差热分析对其热稳定性进行初步研究。
|
| 关 键 词： | 开链冠醚 过渡金属配合物 合成与表征 |
| 文章编号： | 1001-1862(2001)03-420-05 |
| 修稿时间： | 2000年6月19日 |
Synthesis and Characterization of 2,6-Di (8’-quinolinoxy methyl)-4-methyl-anisole and Its Complexes with Silver ( Ⅰ ), Copper ( Ⅱ ) and Nickle ( Ⅱ ) |
| |
| Zhang Qianqian,Ji Zhenping,Xiao Wenjin,Wu Chengtai.Synthesis and Characterization of 2,6-Di (8’-quinolinoxy methyl)-4-methyl-anisole and Its Complexes with Silver ( Ⅰ ), Copper ( Ⅱ ) and Nickle ( Ⅱ )[J].Periodical of Ocean University of China,2001,31(3):420-424. |
| |
| Authors: | Zhang Qianqian Ji Zhenping Xiao Wenjin Wu Chengtai |
| |
| Institution: | Zhang Qianqian1 Ji Zhenping2 Xiao Wenjin 2 Wu Chengtai 2 |
| |
| Abstract: | A novel open chain crown ether 2,6-di (8'-quinolinoxy methyl)-4-methyl-anisole was synthesized and characterized by elemental analysis, IR, 1HNMR and MS. Its complexes with Ag( Ⅰ ), Cu( Ⅱ ) and Ni( Ⅱ ) were synthesized. The elemental analysis shows that with different metal ions, the ratio of metal to ligand is different. The M:L of Ag( Ⅰ ) complex is 1:1, while Cu( Ⅱ ) and Ni( Ⅱ ) is 2:3. The complexes were also examined by thermal analysis. |
| |
| Keywords: | open chain crown ether transition metal complex synthesis and characterization |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
